An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction
文献类型：期刊论文
| 作者 | Liang, Yufan2,3,4; Wang, Lin2,3,4; Zhu, Rong2,3,4; Deng, Lujiang2,3,4; Yang, Yunfang1; Quan, Junmin1; Chen, Jiahua2,3,4; Yang, Zhen1,2,3,4 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2010-10-04 |
| 卷号 | 352期号:14-15页码:2387-2393 |
| 关键词 | Ethyl Glyoxylate Silver Hexafluroantimonate Titanium Chloride-mediated Reaction Vinylogous Mukaiyama Aldol Reaction Chiral Vinylketene Silyl n O-acetals |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201000420 |
| 英文摘要 | Silver hexafluroantimonate was identified as a highly efficient agent to reverse the facial selectivity of the titanium chloride-mediated vinylogous Mukaiyama aldol reaction (VMAR), and this unprecedented reaction provides a concise, diastereoselective synthesis of delta-hydroxy-alpha,gamma-dimethyl-alpha,beta-unsaturated carbonyl units from readily available chiral vinylketene silyl N,O-acetal 6 and ethyl glyoxylate 8. |
| 语种 | 英语 |
| WOS记录号 | WOS:000284003100007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70569]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Quan, Junmin |
| 作者单位 | 1.Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China 2.Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Peking Univ, BNLMS, Coll Chem, Beijing 100871, Peoples R China 4.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Yufan,Wang, Lin,Zhu, Rong,et al. An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(14-15):2387-2393. |
| APA | Liang, Yufan.,Wang, Lin.,Zhu, Rong.,Deng, Lujiang.,Yang, Yunfang.,...&Yang, Zhen.(2010).An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction.ADVANCED SYNTHESIS & CATALYSIS,352(14-15),2387-2393. |
| MLA | Liang, Yufan,et al."An Unprecedented Silver Salt Effect Switches the Facial Selectivity in the Vinylogous Mukaiyama Aldol Reaction".ADVANCED SYNTHESIS & CATALYSIS 352.14-15(2010):2387-2393. |
入库方式： OAI收割
来源：化学研究所
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