New linear pi-conjugated polymers via Suzuki coupling of (1Z, 3Z)-1,4-dibromo-1,4-diaryl-buta-1,3-diene with aromatic diborates: Synthesis and photophysical properties
文献类型:期刊论文
作者 | Liu, Yan1; Chen, Xingguo1; Qin, Jingui1; Yu, Gui2; Liu, Yunqi2 |
刊名 | POLYMER
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出版日期 | 2010-07-22 |
卷号 | 51期号:16页码:3730-3735 |
关键词 | Conjugated Polymer Photophysical Properties Buta-1 3-diene |
ISSN号 | 0032-3861 |
DOI | 10.1016/j.polymer.2010.06.003 |
英文摘要 | A series of new linear pi-conjugated polymers have been synthesized via Suzuki coupling of (1Z, 3Z)-1,4-dibromo-1,4-diaryl-buta-1,3-diene with aromatic diborates. The structures were characterized by NMR spectroscopy, IR spectroscopy and GPC. All of them exhibit good thermal stability with high decomposition temperature over 340 degrees C. It was found that the absorption and emission of the polymers can be adjusted through changing the side aromatic group, and the partial twisted structure of two aromatic groups at the end carbon of buta-1,3-diene unit can hinder the interchain interaction of conjugated main chain and improve the photophysical properties of the polymers in the solid state. The electrochemical and electroluminescent properties of the polymers were primarily studied. (C) 2010 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000280263200016 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/70593] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Xingguo |
作者单位 | 1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Yan,Chen, Xingguo,Qin, Jingui,et al. New linear pi-conjugated polymers via Suzuki coupling of (1Z, 3Z)-1,4-dibromo-1,4-diaryl-buta-1,3-diene with aromatic diborates: Synthesis and photophysical properties[J]. POLYMER,2010,51(16):3730-3735. |
APA | Liu, Yan,Chen, Xingguo,Qin, Jingui,Yu, Gui,&Liu, Yunqi.(2010).New linear pi-conjugated polymers via Suzuki coupling of (1Z, 3Z)-1,4-dibromo-1,4-diaryl-buta-1,3-diene with aromatic diborates: Synthesis and photophysical properties.POLYMER,51(16),3730-3735. |
MLA | Liu, Yan,et al."New linear pi-conjugated polymers via Suzuki coupling of (1Z, 3Z)-1,4-dibromo-1,4-diaryl-buta-1,3-diene with aromatic diborates: Synthesis and photophysical properties".POLYMER 51.16(2010):3730-3735. |
入库方式: OAI收割
来源:化学研究所
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