Catalytic Organic Reactions in CO2/H2O Medium
文献类型：期刊论文
| 作者 | Wu Suxiang; Fan Honglei; Cheng Yan; Wang Qian; Han Buxing |
| 刊名 | PROGRESS IN CHEMISTRY
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 22期号:7页码:1286-1294 |
| 关键词 | Green Chemistry Mixed Green Solvents Co2 H2o Catalysis Organic Reaction |
| ISSN号 | 1005-281X |
| 英文摘要 | Green chemistry is the trend of chemistry in the future. Utilization of green solvents effectively is one of the, important topics in green chemistry. CO2/H2O system is green reaction medium with some unique features, and can be used in different chemical reactions. Especially, it can be used in the reactions catalyzed by weak acids, in which the use of conventional hazardous acids can be avoided. In this review, we first discuss the variation of the acidity of CO2/H2O system with temperature and pressure, then some chemical reactions in CO2/H2O system are discussed, including dehydration reaction, alkylation reaction, citronellal cyclization reaction, diazonium reaction, conversion of polyalcohol to cyclic ether, oxybromination reaction, selective reduction of nitroarenes, polysaccharide hydrolysis, conversion of biomass, hydrolysis of propylene oxide, decarboxylation reaction, oxidation of alcohols, enantioselective sulfoxidation, asymmetric reduction of ketones. Finally, the future directions for the applications of CO2/H2O system in chemical reactions are discussed briefly. |
| 语种 | 英语 |
| WOS记录号 | WOS:000280274000005 |
| 出版者 | CHINESE ACAD SCIENCES |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70597]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han Buxing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu Suxiang,Fan Honglei,Cheng Yan,et al. Catalytic Organic Reactions in CO2/H2O Medium[J]. PROGRESS IN CHEMISTRY,2010,22(7):1286-1294. |
| APA | Wu Suxiang,Fan Honglei,Cheng Yan,Wang Qian,&Han Buxing.(2010).Catalytic Organic Reactions in CO2/H2O Medium.PROGRESS IN CHEMISTRY,22(7),1286-1294. |
| MLA | Wu Suxiang,et al."Catalytic Organic Reactions in CO2/H2O Medium".PROGRESS IN CHEMISTRY 22.7(2010):1286-1294. |
入库方式： OAI收割
来源：化学研究所
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