A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-Me2Si[2-Me-4-Ph-Ind](2)ZrCl2/MAO
文献类型:期刊论文
作者 | Zhang, Chuanhui1,2; Niu, Hui1; Dong, Jin-Yong1 |
刊名 | POLYMER BULLETIN
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出版日期 | 2010-11-01 |
卷号 | 65期号:8页码:779-786 |
关键词 | Propylene Polymerization Metallocene Catalysts Alkylzinc Compounds Copolymerization Chain Transfer |
ISSN号 | 0170-0839 |
DOI | 10.1007/s00289-010-0245-6 |
英文摘要 | The polymerization of propylene combined with bis(6-heptenyl)zinc (BHZ) catalyzed by rac-Me2Si[2-Me-4-Ph-Ind](2)ZrCl2/MAO was investigated. BHZ acts as both a comonomer and a chain transfer reagent, which was verified by H-1 NMR and C-13 NMR spectra. A novel effect of BHZ on the molecular weight and rheologic properties of the product was explained by the production of LCB. |
语种 | 英语 |
WOS记录号 | WOS:000283508800003 |
出版者 | SPRINGER |
源URL | [http://ir.iccas.ac.cn/handle/121111/70665] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Chuanhui |
作者单位 | 1.Chinese Acad Sci, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Chuanhui,Niu, Hui,Dong, Jin-Yong. A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-Me2Si[2-Me-4-Ph-Ind](2)ZrCl2/MAO[J]. POLYMER BULLETIN,2010,65(8):779-786. |
APA | Zhang, Chuanhui,Niu, Hui,&Dong, Jin-Yong.(2010).A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-Me2Si[2-Me-4-Ph-Ind](2)ZrCl2/MAO.POLYMER BULLETIN,65(8),779-786. |
MLA | Zhang, Chuanhui,et al."A novel effect of bis(6-heptenyl)zinc on the molecular weight and rheologic performance of polypropylene produced by rac-Me2Si[2-Me-4-Ph-Ind](2)ZrCl2/MAO".POLYMER BULLETIN 65.8(2010):779-786. |
入库方式: OAI收割
来源:化学研究所
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