Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction
文献类型：期刊论文
| 作者 | Zhao Hai-yan1; Li Jing1; Xing Yong-heng1; Pu Zhi-feng2; Bai Feng-ying1; Ge Mao-fa2; Niu Shu-yun1 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2010-09-25 |
| 卷号 | 26期号:5页码:687-692 |
| 关键词 | Tren-schiff Base Crystal Structure Hydrogen Bond Quantum Chemistry |
| ISSN号 | 1005-9040 |
| 英文摘要 | The new self-assembly tripodal hexadentate Schiff base compound, C27H30N4O3, derived from tris(2-aminoethyl)amine(tren) with salicylaldehyde and its manganese(III) complex [(C27H27N4O3)Mn]center dot CH3OH(1) were designed and synthesized by original self-assembly reaction at room temperature in the solution of methanol. Both the compounds were characterized by elemental analysis, IR spectrometry, UV-Vis spectroscopy and X-ray single crystal diffraction. It is noteworthy that the tripodal hexadentate Schiff base ligand effectively encapsulates the manganese(III) ion and enforces a six-coordinate geometry in complex 1 with the apical nitrogen atom of tren-Schiff base remaining unbound to the metal. It is found that there are several intra-molecular hydrogen bonds in them(C-H center dot center dot center dot O and O-H center dot center dot center dot N). In addition, quantum chemistry calculations were also performed and discussed in detail. These results are consistent with the structural analyses of them. |
| 语种 | 英语 |
| WOS记录号 | WOS:000283618500004 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70707]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing Yong-heng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Hai-yan,Li Jing,Xing Yong-heng,et al. Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2010,26(5):687-692. |
| APA | Zhao Hai-yan.,Li Jing.,Xing Yong-heng.,Pu Zhi-feng.,Bai Feng-ying.,...&Niu Shu-yun.(2010).Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,26(5),687-692. |
| MLA | Zhao Hai-yan,et al."Synthesis, Structure and Properties of Tren-Schiff Base Compound and Its Manganese(III) Complex by Original Self-assembly Reaction".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 26.5(2010):687-692. |
入库方式： OAI收割
来源：化学研究所
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