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Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres
文献类型：期刊论文
| 作者 | Wang, Xi1,2; Wu, Xing-Long2,3; Guo, Yu-Guo3; Zhong, Yeteng1,2; Cao, Xinqiang1,2; Ma, Ying1; Yao, Jiannian1 |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2010-05-25 |
| 卷号 | 20期号:10页码:1680-1686 |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.200902295 |
| 英文摘要 | Single-, double-, and triple-shelled hollow spheres assembled by Co3O4 nanosheets are successfully synthesized through a novel method. The possible formation mechanism of these novel structures was investigated using powder X-ray diffraction, scanning and transmission electron microscopies, Fourier transform IR, X-ray photoelectron spectroscopy, and thermogravimetric analysis. Both poly(vinylpyrrolidone) (PVP) soft templates and the formation of cobalt glycolate play key roles in the formation of these novel multishelled hollow structures. When tested as the anode material in lithium-ion batteries (LIBs), these multishelled microspheres exhibit excellent cycling performance, good rate capacity, and enhanced lithium storage capacity. This superior cyclic stability and capacity result from the synergetic effect of small diffusion lengths in the nanosheet building blocks and sufficient void space to buffer the volume expansion. This facile strategy may be extended to synthesize other transition metal oxide materials with hollow multishelled micro-inanostrucutures, which may find application in sensors and catalysts due to their unique structural features. |
| 语种 | 英语 |
| WOS记录号 | WOS:000278597100018 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70711]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Xi |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, BNLMS, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xi,Wu, Xing-Long,Guo, Yu-Guo,et al. Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres[J]. ADVANCED FUNCTIONAL MATERIALS,2010,20(10):1680-1686. |
| APA | Wang, Xi.,Wu, Xing-Long.,Guo, Yu-Guo.,Zhong, Yeteng.,Cao, Xinqiang.,...&Yao, Jiannian.(2010).Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres.ADVANCED FUNCTIONAL MATERIALS,20(10),1680-1686. |
| MLA | Wang, Xi,et al."Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres".ADVANCED FUNCTIONAL MATERIALS 20.10(2010):1680-1686. |
入库方式： OAI收割
来源：化学研究所
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