Synthesis and structural characterization of different topological coordination polymers based on tunable Cu4Br4-mIm secondary building units and macrocyclic azacalixaromatics
文献类型：期刊论文
| 作者 | Wang, Li-Xia2; Zhao, Liang1; Wang, De-Xian2; Wang, Mei-Xiang1,2 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 183期号:12页码:3010-3016 |
| 关键词 | Coordination Network Macrocyclic Ligand Copper Halide Luminescence |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2010.10.011 |
| 英文摘要 | The coordination self-assembly between the macrocyclic ligand tetraazacalix[4]pyrimidine (TAPM) with cubane-like copper halides (Cu4X4) produced five coordination polymers 1-5 {Cu4Br4-mIm(TAPM)}(n) (m = 0 (1), 1(2), 2 (3), 3 (4) and 4 (5)). X-ray single crystal analysis revealed that the Br:I ratio in the Cu4X4 cores serves as a controlling factor to fine-tune the geometries of Cu4X4 and therefore induce the conformation variation of tetraazacalix[4]pyrimidine. Consequently, two different topological nets, dia and lcs, were successfully constructed based on tetrahedrally coordinated Cu4X4 secondary building units and the flexible macrocyclic quadridentate ligand TAPM. The structure details of 1-5 as porous materials are analyzed, which shows a solvent accessible volume within the range of 27-35%. Compounds 1-5 exhibit luminescence properties with the peak maximum at around 476-488 nm. (c) 2010 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000285431100037 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70785]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Liang |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Li-Xia,Zhao, Liang,Wang, De-Xian,et al. Synthesis and structural characterization of different topological coordination polymers based on tunable Cu4Br4-mIm secondary building units and macrocyclic azacalixaromatics[J]. JOURNAL OF SOLID STATE CHEMISTRY,2010,183(12):3010-3016. |
| APA | Wang, Li-Xia,Zhao, Liang,Wang, De-Xian,&Wang, Mei-Xiang.(2010).Synthesis and structural characterization of different topological coordination polymers based on tunable Cu4Br4-mIm secondary building units and macrocyclic azacalixaromatics.JOURNAL OF SOLID STATE CHEMISTRY,183(12),3010-3016. |
| MLA | Wang, Li-Xia,et al."Synthesis and structural characterization of different topological coordination polymers based on tunable Cu4Br4-mIm secondary building units and macrocyclic azacalixaromatics".JOURNAL OF SOLID STATE CHEMISTRY 183.12(2010):3010-3016. |
入库方式： OAI收割
来源：化学研究所
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