Ni2+-containing ionic liquid immobilized on silica: Effective catalyst for styrene oxidation with H2O2 at solvent-free condition
文献类型：期刊论文
| 作者 | Liu, Gang; Hou, Minqiang; Song, Jiyuan; Zhang, Zhaofu; Wu, Tainbin; Han, Buxing |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2010-02-01 |
| 卷号 | 316期号:1-2页码:90-94 |
| 关键词 | Ionic Liquid Heterogeneous Catalysis Nickel(Ii) Oxidation Solvent-free Reactions |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2009.10.004 |
| 英文摘要 | In this work we synthesized Ni2+-containing ionic liquid (IL) 1-methyl-3-[(triethoxysilyl)propyl] imidazolium chloride (TMICl) immobilized on silica to catalyze styrene oxidation with H2O2 for producing benzaldehyde. The catalyst was characterized by Fourier transform infrared (FT-IR) spectroscopy, UV-vis spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen sorption techniques. The effects of reaction time, reaction temperature, and molar ratio of styrene and H2O2 on the conversion and selectivity were studied at solvent-free condition and in acetonitrile. It was demonstrated that the catalyst was very effective for the reaction. The unique advantage of the catalyst was that the reaction could be carried out at solvent-free condition. This advantage resulted mainly from the fact that both of the reactants, styrene and H2O2, are miscible with the IL, and the Ni2+ was coordinated by the immobilized IL that allowed both reactants to access to active sites of the catalyst effectively. (C) 2009 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000273890300012 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70809]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Gang,Hou, Minqiang,Song, Jiyuan,et al. Ni2+-containing ionic liquid immobilized on silica: Effective catalyst for styrene oxidation with H2O2 at solvent-free condition[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2010,316(1-2):90-94. |
| APA | Liu, Gang,Hou, Minqiang,Song, Jiyuan,Zhang, Zhaofu,Wu, Tainbin,&Han, Buxing.(2010).Ni2+-containing ionic liquid immobilized on silica: Effective catalyst for styrene oxidation with H2O2 at solvent-free condition.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,316(1-2),90-94. |
| MLA | Liu, Gang,et al."Ni2+-containing ionic liquid immobilized on silica: Effective catalyst for styrene oxidation with H2O2 at solvent-free condition".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 316.1-2(2010):90-94. |
入库方式： OAI收割
来源：化学研究所
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