Low-Bandgap Conjugated Donor-Acceptor Copolymers Based on Porphyrin with Strong Two-Photon Absorption
文献类型：期刊论文
| 作者 | Huang, Xuebin3,4,5; Shi, Qinqin3,4,6; Chen, Wei-Qiang1,2; Zhu, Chunli3,4,5; Zhou, Weiyi3,4,6; Zhao, Zhen3,4; Duan, Xuan-Ming1,2; Zhan, Xiaowei3,4 |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2010-12-14 |
| 卷号 | 43期号:23页码:9620-9626 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/ma102275h |
| 英文摘要 | Two new low-bandgap, conjugated donor (D) acceptor (A) copolymers of porphyrin with 2,3-bis(4-trifluoromethylphenyl)pyrido[3,4-b]pyrazine (P1) and perylene diimide (P2) were synthesized by Sonogashira coupling polymerization and compared with porphyrin-dithienothiophene D-D copolymer (P3). All these polymers possess good thermal stability with decomposition temperatures over 300 degrees C. Polymers P1 and P2 in films exhibit strong absorption in near-IR (820-950 nm) with optical bandgaps as low as 1.15 eV; their Q-bands red shift 60 190 nm compared to that of P3, while the Soret bands are similar. The HOMO (-5.3 to -5.4 eV) and LUMO (-3.6 to -4.0 eV) of the D-A polymers are lower than that of the D D polymer. Two-photon absorption (2PA) properties of the polymers were investigated by the femtosecond Z-scan method. The D A polymer P2 exhibits 2PA cross sections over 7000 GM/repeat unit at telecommunication wavelengths (1320 and 1520 nm), larger than that of PI and P3, due to the very strong, rigid, and coplanar perylene diimide acceptor and strong D-A intramolecular charge transfer. |
| 语种 | 英语 |
| WOS记录号 | WOS:000284967000009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70893]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Duan, Xuan-Ming |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Lab Organ Nanophoton, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convent & Funct Mat, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 5.Beijing Inst Technol, Dept Chem, Beijing 100083, Peoples R China 6.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Xuebin,Shi, Qinqin,Chen, Wei-Qiang,et al. Low-Bandgap Conjugated Donor-Acceptor Copolymers Based on Porphyrin with Strong Two-Photon Absorption[J]. MACROMOLECULES,2010,43(23):9620-9626. |
| APA | Huang, Xuebin.,Shi, Qinqin.,Chen, Wei-Qiang.,Zhu, Chunli.,Zhou, Weiyi.,...&Zhan, Xiaowei.(2010).Low-Bandgap Conjugated Donor-Acceptor Copolymers Based on Porphyrin with Strong Two-Photon Absorption.MACROMOLECULES,43(23),9620-9626. |
| MLA | Huang, Xuebin,et al."Low-Bandgap Conjugated Donor-Acceptor Copolymers Based on Porphyrin with Strong Two-Photon Absorption".MACROMOLECULES 43.23(2010):9620-9626. |
入库方式： OAI收割
来源：化学研究所
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