Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands
文献类型：期刊论文
| 作者 | Xie, Yan1,4; Bai, Feng Ying1; Li, Jing1; Xing, Yong Heng1; Wang, Zhuo1; Zhao, Hai Yan1; Pu, Zhi Feng2; Ge, Mao Fa2; Shi, Zhan3 |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2010-11-01 |
| 卷号 | 77期号:4页码:749-754 |
| 关键词 | Coordination Polymer Suberic Acid Synthesis Crystal Structure Surface Photovoltage Spectrum |
| ISSN号 | 1386-1425 |
| DOI | 10.1016/j.saa.2010.07.009 |
| 英文摘要 | Two-dimensional coordination polymers, [M(C8H12O4)(C10H8N2)]center dot H2O [M = Co (1), Cd (2); C10H8N2 = 4,4-bipyridine, C8H14O4 = subaric acid] were obtained from the reaction of the metal salts, bipy and subaric acid at 180 C and characterized by elemental analysis, infrared spectrum, and single-crystal X-ray diffraction and surface photovoltage spectrum (SPS). The single-crystal X-ray diffraction showed that the subaric ligand in the two complexes exhibits two types of modes coordinating to transition metal ions, resulting in the formation of a 1D infinite chain along the c-axis. In addition, the results of SPS for complexes 1 and 2 indicate that these two complexes exhibit positive surface photovoltage responses in the range of 300-800 nm, which can be assigned to LMCT and MLCT, respectively. And the SPS of complex 1 also can be assigned to the d -> d* electronic transition. The SPS spectra of the two complexes are consistent with their UV-vis spectra. (C) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000283906100006 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70963]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yong Heng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Yan,Bai, Feng Ying,Li, Jing,et al. Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2010,77(4):749-754. |
| APA | Xie, Yan.,Bai, Feng Ying.,Li, Jing.,Xing, Yong Heng.,Wang, Zhuo.,...&Shi, Zhan.(2010).Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,77(4),749-754. |
| MLA | Xie, Yan,et al."Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 77.4(2010):749-754. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。