New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction
文献类型：期刊论文
| 作者 | Li, Zhong'an1; Wu, Wenbo1; Ye, Cheng2; Qin, Jingui1; Li, Zhen1 |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2010-04-15 |
| 卷号 | 211期号:8页码:916-923 |
| 关键词 | Hyperbranched Polymer Monomers Nonlinear Optics Sonogashira Coupling Reaction Synthesis |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.200900605 |
| 英文摘要 | In this paper, a facile route was designed to prepare a new AB(2)-type polymer P1 via simple Sonogashira coupling reaction, also its corresponding linear analog (P2) was obtained from AB monomer for comparison. Despite the relatively lower loading density of the effective chromophore moieties, P1 demonstrated higher second-harmonic coefficient (153.9 pm . V-1) than that of P2 (98.2 pm . V-1), due to the three-dimensional spatial isolation effect of the hyperbranched structure. The good results of P2 also indicated that the ladder shape may help to solve the problem existing in main-chain polymers, the low poling efficiency. |
| 语种 | 英语 |
| WOS记录号 | WOS:000277354500009 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70983]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zhen |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhong'an,Wu, Wenbo,Ye, Cheng,et al. New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2010,211(8):916-923. |
| APA | Li, Zhong'an,Wu, Wenbo,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2010).New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction.MACROMOLECULAR CHEMISTRY AND PHYSICS,211(8),916-923. |
| MLA | Li, Zhong'an,et al."New Second-Order Nonlinear Optical Polymers Derived from AB(2) and AB Monomers via Sonogashira Coupling Reaction".MACROMOLECULAR CHEMISTRY AND PHYSICS 211.8(2010):916-923. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。