PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS
文献类型：期刊论文
| 作者 | Jie, Su-yun3; Sun, Wen-hua1,2 ; Xiao, Tianpengfei1,2
|
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 28期号:3页码:299-304 |
| 关键词 | Iron Complex Cobalt Complex Ethylene Oligomerization Ethylene Polymerization |
| ISSN号 | 0256-7679 |
| DOI | 10.1007/s10118-010-0034-6 |
| 英文摘要 | The discovery of highly active 2,6-bis(imino)pyridyl iron and cobalt complexes provided a milestone of late-transition metal catalysts for ethylene oligomerization and polymerization with being currently investigated for the scale-up process. The crucial problems are remaining in the catalytic systems: the catalytic systems targeting ethylene polymerization produce more oligomers at elevated reaction temperatures, however, there is a recognizable amount of high-molecular-weight polyethylene remained in the modified catalytic system for the oligomerization process. Beyond the modification of bis(imino)pyridyl metal complexes, several alternative procatalysts' models have been developed in our group. This review highlighted the achievements in exploring new iron and cobalt complexes with tridentate NNN ligands as procatalysts for ethylene oligomerization and polymerization. |
| 语种 | 英语 |
| WOS记录号 | WOS:000279111400002 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70995]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-hua |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Zhejiang Univ, State Key Lab Chem Engn, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jie, Su-yun,Sun, Wen-hua,Xiao, Tianpengfei. PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2010,28(3):299-304. |
| APA | Jie, Su-yun,Sun, Wen-hua,&Xiao, Tianpengfei.(2010).PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS.CHINESE JOURNAL OF POLYMER SCIENCE,28(3),299-304. |
| MLA | Jie, Su-yun,et al."PROSPECTS AND CRUCIAL PROBLEMS IN OLIGOMERIZATION AND POLYMERIZATION WITH IRON AND COBALT COMPLEX CATALYSTS".CHINESE JOURNAL OF POLYMER SCIENCE 28.3(2010):299-304. |
入库方式： OAI收割
来源：化学研究所
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