Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides
文献类型：期刊论文
| 作者 | Yuan, Shifang1,2,3; Zhang, Liping1,2,3; Liu, Diansheng1; Sun, Wen-Hua2,3
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| 刊名 | MACROMOLECULAR RESEARCH
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| 出版日期 | 2010-07-01 |
| 卷号 | 18期号:7页码:690-694 |
| ISSN号 | 1598-5032 |
| 关键词 | Beta-diketiminate Zirconium Ethylene Polymerization Molecular Weight Polyethylene |
| DOI | 10.1007/s13233-010-0704-9 |
| 英文摘要 | Unsymmetrical beta-diketiminato zirconium chlorides were prepared by an elimination reaction of ZrCl(4) with the corresponding beta-diketiminato lithium atoms [Li{N(Dipp)C(R)CHC((t)Bu)NH}](2) (Dipp=2,6-(i)Pr(2)C(6)H(3); R=Ph or Me). Two zirconium complexes were fully characterized by elemental, (1)H, and (13)C NMR analyses, and confirmed by single-crystal X-ray diffraction. These complexes, activated with methylaluminoxane (MAO) showed good activity towards ethylene polymerization, and produced high molecular weight polyethylene. |
| 语种 | 英语 |
| 出版者 | SPRINGER |
| WOS记录号 | WOS:000282470900012 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70997]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Diansheng |
| 作者单位 | 1.Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Shifang,Zhang, Liping,Liu, Diansheng,et al. Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides[J]. MACROMOLECULAR RESEARCH,2010,18(7):690-694. |
| APA | Yuan, Shifang,Zhang, Liping,Liu, Diansheng,&Sun, Wen-Hua.(2010).Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides.MACROMOLECULAR RESEARCH,18(7),690-694. |
| MLA | Yuan, Shifang,et al."Synthesis and Ethylene Polymerization by beta-Diketiminato Zirconium Chlorides".MACROMOLECULAR RESEARCH 18.7(2010):690-694. |
入库方式： OAI收割
来源：化学研究所
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