Electrospinning in compressed carbon dioxide: Hollow or open-cell fiber formation with a single nozzle configuration
文献类型：期刊论文
| 作者 | Liu, Jun1; Shen, Zhihao2; Lee, Sang-Ho3; Marquez, Manuel4; McHugh, Mark A.1 |
| 刊名 | JOURNAL OF SUPERCRITICAL FLUIDS
 |
| 出版日期 | 2010-06-01 |
| 卷号 | 53期号:1-3页码:142-150 |
| 关键词 | Open-cell And Hollow Fibers Electrospinning Compressed Carbon Dioxide |
| ISSN号 | 0896-8446 |
| DOI | 10.1016/j.supflu.2010.02.016 |
| 英文摘要 | Electrospinning is combined with the PCA (precipitation with a compressed fluid antisolvent) process (ES-PCA) to produce micron to submicron polymeric fibers with open-cell or hollow core morphology. CO2 is used as the compressed gas of choice and the impact of CO2 pressure (density) on fiber morphology is demonstrated for the poly(vinyl pyrrolidone) (PVP)-dichloromethane, PVP-ethanol, poly(vinylidenefluoride) (PVDF)-dimethylacetamide, and PVDF-dimethyl formamide systems. CO2, which is in excess for this process, rapidly extracts solvent from the surface of the liquid jet to form a vitrified polymer skin and also dissolves into the liquid jet and induces the polymer-solvent solution to phase separate. The ES-PCA technique has the advantage that fiber morphology can be easily controlled via pressure and pressures in excess of 100 bar are not needed to obtain a variety of different fiber morphologies. The fiber formation process correlates closely with the binary solvent-CO2 and ternary polymer-solvent-CO2 phase behavior. (C) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000278240000023 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/70999]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | McHugh, Mark A. |
| 作者单位 | 1.Virginia Commonwealth Univ, Dept Chem & Life Sci Engn, Richmond, VA 23284 USA 2.Peking Univ, Coll Chem & Mol Engn, Key Lab Polymer Chem & Phys,Minist Educ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 3.Dong A Univ, Dept Chem Engn, Pusan, South Korea 4.YNano LLC, Midlothian, VA 23113 USA |
| 推荐引用方式 GB/T 7714 | Liu, Jun,Shen, Zhihao,Lee, Sang-Ho,et al. Electrospinning in compressed carbon dioxide: Hollow or open-cell fiber formation with a single nozzle configuration[J]. JOURNAL OF SUPERCRITICAL FLUIDS,2010,53(1-3):142-150. |
| APA | Liu, Jun,Shen, Zhihao,Lee, Sang-Ho,Marquez, Manuel,&McHugh, Mark A..(2010).Electrospinning in compressed carbon dioxide: Hollow or open-cell fiber formation with a single nozzle configuration.JOURNAL OF SUPERCRITICAL FLUIDS,53(1-3),142-150. |
| MLA | Liu, Jun,et al."Electrospinning in compressed carbon dioxide: Hollow or open-cell fiber formation with a single nozzle configuration".JOURNAL OF SUPERCRITICAL FLUIDS 53.1-3(2010):142-150. |
入库方式： OAI收割
来源：化学研究所
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