Photodissociation and DFT investigation of V+(C2H4)(n) (n=1-3) complexes
文献类型：期刊论文
| 作者 | Yuan, Jinyun; Zhang, Zeng-Guang; Zhao, Yuchao; Hou, Gao-Lei; Xu, Hong-Guang; Zheng, Weijun |
| 刊名 | INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
 |
| 出版日期 | 2010-07-15 |
| 卷号 | 295期号:1-2页码:36-42 |
| 关键词 | Mass Spectrometry Mass-selection Photodissociation Vanadium-ethene Complex |
| ISSN号 | 1387-3806 |
| DOI | 10.1016/j.ijms.2010.06.018 |
| 英文摘要 | V+(C2H4)(n) were produced in a supersonic molecular beam by laser vaporization and were mass-analyzed with a reflectron time-of-flight mass spectrometer. V(C2H4)(n) (n = 1-3) are predominant mass peaks in the mass spectrum. These species were mass-selected and photodissociated with 1064, 532 and 355 nm photons. Dissociation occurs by elimination of neutral ethene molecules. The fragment ion yields were studied as a function of photon fluxes in order to give insight into the dissociation mechanisms. The geometric structures, bond dissociation energies and ground electronic state of V(C2H4)(n) (n = 1-4) were investigated using density functional theory (DFT). It has been confirmed that the most stable structures of V+(C2H4)(n) are all in quintet states. (C) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000281919300006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71019]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zheng, Weijun |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Jinyun,Zhang, Zeng-Guang,Zhao, Yuchao,et al. Photodissociation and DFT investigation of V+(C2H4)(n) (n=1-3) complexes[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,2010,295(1-2):36-42. |
| APA | Yuan, Jinyun,Zhang, Zeng-Guang,Zhao, Yuchao,Hou, Gao-Lei,Xu, Hong-Guang,&Zheng, Weijun.(2010).Photodissociation and DFT investigation of V+(C2H4)(n) (n=1-3) complexes.INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,295(1-2),36-42. |
| MLA | Yuan, Jinyun,et al."Photodissociation and DFT investigation of V+(C2H4)(n) (n=1-3) complexes".INTERNATIONAL JOURNAL OF MASS SPECTROMETRY 295.1-2(2010):36-42. |
入库方式： OAI收割
来源：化学研究所
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