中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance

文献类型:期刊论文

作者Luo Fa-Liang1,2; Chen Tian-Lu2
刊名CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
出版日期2010-11-01
卷号38期号:11页码:1609-1614
关键词Cresol Red Optical Ph Sensor Polyvinyl Alcohol Membrane
ISSN号0253-3820
DOI10.3724/SP.J.1096.2010.01609
英文摘要An optical chemical pH sensitive membrane for optical chemical pH sensors has been developed by covalently immobilizing cresol red on optical transparent cross-linked polyvinyl alcohol (PVA) membrane surfaces by using acrylamide as couple agent and Fe(2+)/H(2)O(2) as initiator. The performance of the pH sensitive membrane was investigated. The results showed that the pH sensitive membrane had some excellent features. Firstly, the sensitive membrane still held two pH response intervals and the two response intervals were expanded from pH 0.15 -1.18 and pH 7.33 -8.94 of cresol red solution to 0.1 -5 mol/L [H(+)] and pH = 7.97 -12.26. Secondly, the optical chemical pH sensitive membrane had rapid response time (<25 s), good reproducibility, reversibility, excellent optical and storage stability. Lastly, the typical feature of the optical chemical pH sensitive membrane was easiness of fabrication. All of these show that the pH sensitive membrane is suitable to be used as a sensitive layer for optical pH sensor.
语种英语
WOS记录号WOS:000285283300015
出版者ELSEVIER SCIENCE INC
源URL[http://ir.iccas.ac.cn/handle/121111/71053]  
专题中国科学院化学研究所
通讯作者Luo Fa-Liang
作者单位1.Ningxia Univ, Prov Key Lab Energy & Chem Engn, Yinchuan 750021, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Luo Fa-Liang,Chen Tian-Lu. Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2010,38(11):1609-1614.
APA Luo Fa-Liang,&Chen Tian-Lu.(2010).Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,38(11),1609-1614.
MLA Luo Fa-Liang,et al."Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 38.11(2010):1609-1614.

入库方式: OAI收割

来源:化学研究所

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