Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance
文献类型:期刊论文
作者 | Luo Fa-Liang1,2; Chen Tian-Lu2 |
刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
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出版日期 | 2010-11-01 |
卷号 | 38期号:11页码:1609-1614 |
关键词 | Cresol Red Optical Ph Sensor Polyvinyl Alcohol Membrane |
ISSN号 | 0253-3820 |
DOI | 10.3724/SP.J.1096.2010.01609 |
英文摘要 | An optical chemical pH sensitive membrane for optical chemical pH sensors has been developed by covalently immobilizing cresol red on optical transparent cross-linked polyvinyl alcohol (PVA) membrane surfaces by using acrylamide as couple agent and Fe(2+)/H(2)O(2) as initiator. The performance of the pH sensitive membrane was investigated. The results showed that the pH sensitive membrane had some excellent features. Firstly, the sensitive membrane still held two pH response intervals and the two response intervals were expanded from pH 0.15 -1.18 and pH 7.33 -8.94 of cresol red solution to 0.1 -5 mol/L [H(+)] and pH = 7.97 -12.26. Secondly, the optical chemical pH sensitive membrane had rapid response time (<25 s), good reproducibility, reversibility, excellent optical and storage stability. Lastly, the typical feature of the optical chemical pH sensitive membrane was easiness of fabrication. All of these show that the pH sensitive membrane is suitable to be used as a sensitive layer for optical pH sensor. |
语种 | 英语 |
WOS记录号 | WOS:000285283300015 |
出版者 | ELSEVIER SCIENCE INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/71053] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Luo Fa-Liang |
作者单位 | 1.Ningxia Univ, Prov Key Lab Energy & Chem Engn, Yinchuan 750021, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Luo Fa-Liang,Chen Tian-Lu. Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2010,38(11):1609-1614. |
APA | Luo Fa-Liang,&Chen Tian-Lu.(2010).Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,38(11),1609-1614. |
MLA | Luo Fa-Liang,et al."Preparation of High Hydrophilic Optical Chemical pH Sensitive Membranes via Covalent Immobilization Method and Its Performance".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 38.11(2010):1609-1614. |
入库方式: OAI收割
来源:化学研究所
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