中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Large Enhancement in Conductivity of Polyaniline Films by Cold Stretching

文献类型:期刊论文

作者Xiao, Hong-Mei1; Zhang, Wei-Dong1; Lv, Chen1; Fu, Shao-Yun1; Wan, Mei-Xiang1,2; Mai, Yiu-Wing3
刊名MACROMOLECULAR CHEMISTRY AND PHYSICS
出版日期2010-05-17
卷号211期号:10页码:1109-1116
关键词Conducting Polymers Cold Stretching Electrical Conductivity Polyaniline Film Tension
ISSN号1022-1352
DOI10.1002/macp.200900711
英文摘要The hot-stretching method has been well accepted for enhancing the electrical conductivity of conducting polymer films. High temperature is the prerequisite to soften the polymer to highly align and elongate the polymeric molecular chains. In this study, the cold-stretching method is proposed for the first time to enhance the conductivity of conducting polymeric films. Polyaniline (PANI) films are stretched at room temperature to different strain levels. It is observed that the applied strain has significant effects on the morphology, molecular chain structure, crystallinity, and crosslinking of the PANI films. As a result, the conductivity of PANI films is effectively increased by the cold-stretching process. Particularly, a maximum conductivity with an 18.4-fold increase in the direction parallel to the stretched direction is obtained when the elastic limit strain is applied. Compared to hot stretching, cold stretching is unique due to the extremely low dimensional change and very high efficiency achieved.
语种英语
WOS记录号WOS:000278484800004
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/71129]  
专题中国科学院化学研究所
通讯作者Fu, Shao-Yun
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
3.Univ Sydney, CAMT, Sch Aerosp Mech & Mechatron Engn J07, Sydney, NSW 2006, Australia
推荐引用方式
GB/T 7714
Xiao, Hong-Mei,Zhang, Wei-Dong,Lv, Chen,et al. Large Enhancement in Conductivity of Polyaniline Films by Cold Stretching[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2010,211(10):1109-1116.
APA Xiao, Hong-Mei,Zhang, Wei-Dong,Lv, Chen,Fu, Shao-Yun,Wan, Mei-Xiang,&Mai, Yiu-Wing.(2010).Large Enhancement in Conductivity of Polyaniline Films by Cold Stretching.MACROMOLECULAR CHEMISTRY AND PHYSICS,211(10),1109-1116.
MLA Xiao, Hong-Mei,et al."Large Enhancement in Conductivity of Polyaniline Films by Cold Stretching".MACROMOLECULAR CHEMISTRY AND PHYSICS 211.10(2010):1109-1116.

入库方式: OAI收割

来源:化学研究所

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