N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene
文献类型：期刊论文
| 作者 | Yang, Huawei1,2; Luan, Shifang1; Zhao, Jie1,2; Shi, Hengchong1,2; Shi, Qiang1; Yin, Jinghua1; Stagnaro, Paola3 |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 70期号:12页码:961-966 |
| 关键词 | Styrene-b-(Ethylene-co-butylene)-b-styrene Radical Functionalization Modification Glycidyl Methacrylate N-vinyl Pyrrolidone |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2010.10.001 |
| 英文摘要 | N-vinyl pyrrolidone (NVP)-assisted free radical functionalization of glycidyl methacrylate (GMA) onto styrene-b-(ethylene-co-butylene)-b-styrene (SEBS) was investigated to attempt to overcome the low grafting reactivity of GMA and the low efficiency of the styrene (St)-assisted functionalization method. By using the optimal amount of NVP, the degree of GMA grafting was increased by at least 7.5 and 2.5-fold when compared to GMA alone and the St-assisted grafting procedure, respectively. Also, no apparent cross-linking or degradation reactions of SEBS were observed. It was proposed that NVP reacted first with SEBS macroradicals, and then the resulting NVP-macroradicals copolymerized with GMA to produce high degrees of grafting of both GMA and NVP onto SEBS. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000285326300005 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71177]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Luan, Shifang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.CNR, Ist Studio Macromol, I-16149 Genoa, Italy |
| 推荐引用方式 GB/T 7714 | Yang, Huawei,Luan, Shifang,Zhao, Jie,et al. N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene[J]. REACTIVE & FUNCTIONAL POLYMERS,2010,70(12):961-966. |
| APA | Yang, Huawei.,Luan, Shifang.,Zhao, Jie.,Shi, Hengchong.,Shi, Qiang.,...&Stagnaro, Paola.(2010).N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene.REACTIVE & FUNCTIONAL POLYMERS,70(12),961-966. |
| MLA | Yang, Huawei,et al."N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene".REACTIVE & FUNCTIONAL POLYMERS 70.12(2010):961-966. |
入库方式： OAI收割
来源：化学研究所
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