Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices
文献类型:期刊论文
作者 | Zheng, Weijun1,2; Kim, Y. Seol1; Kaiser, Ralf I.1,3 |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
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出版日期 | 2011 |
卷号 | 13期号:35页码:15749-15754 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c1cp20528e |
英文摘要 | We investigated the irradiation of low temperature (H2O)-O-18/N-2 ice mixtures with energetic electrons in an ultrahigh vacuum chamber. The newly formed species, such as nitric oxide ((NO)-O-18), nitrous oxide ((NNO)-O-18), hydrogen peroxide ((H2O2)-O-18) and hydrazine (N2H4), were identified in the experiments with infrared absorption spectroscopy and mass spectrometry. The results suggest that the unimolecular decomposition of water molecules within water ices at 10 K can lead to the formation of transient, suprathermal oxygen atoms. These oxygen atoms may play an important role in the formation of oxygen-containing biomolecules such as amino acids and sugar, as well as the decomposition of the biomolecules in the ices. |
语种 | 英语 |
WOS记录号 | WOS:000294167700002 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.iccas.ac.cn/handle/121111/71291] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zheng, Weijun |
作者单位 | 1.Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 3.Univ Hawaii Manoa, NASA Astrobiol Inst, Honolulu, HI 96822 USA |
推荐引用方式 GB/T 7714 | Zheng, Weijun,Kim, Y. Seol,Kaiser, Ralf I.. Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2011,13(35):15749-15754. |
APA | Zheng, Weijun,Kim, Y. Seol,&Kaiser, Ralf I..(2011).Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,13(35),15749-15754. |
MLA | Zheng, Weijun,et al."Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 13.35(2011):15749-15754. |
入库方式: OAI收割
来源:化学研究所
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