中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices

文献类型:期刊论文

作者Zheng, Weijun1,2; Kim, Y. Seol1; Kaiser, Ralf I.1,3
刊名PHYSICAL CHEMISTRY CHEMICAL PHYSICS
出版日期2011
卷号13期号:35页码:15749-15754
ISSN号1463-9076
DOI10.1039/c1cp20528e
英文摘要We investigated the irradiation of low temperature (H2O)-O-18/N-2 ice mixtures with energetic electrons in an ultrahigh vacuum chamber. The newly formed species, such as nitric oxide ((NO)-O-18), nitrous oxide ((NNO)-O-18), hydrogen peroxide ((H2O2)-O-18) and hydrazine (N2H4), were identified in the experiments with infrared absorption spectroscopy and mass spectrometry. The results suggest that the unimolecular decomposition of water molecules within water ices at 10 K can lead to the formation of transient, suprathermal oxygen atoms. These oxygen atoms may play an important role in the formation of oxygen-containing biomolecules such as amino acids and sugar, as well as the decomposition of the biomolecules in the ices.
语种英语
WOS记录号WOS:000294167700002
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/71291]  
专题中国科学院化学研究所
通讯作者Zheng, Weijun
作者单位1.Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China
3.Univ Hawaii Manoa, NASA Astrobiol Inst, Honolulu, HI 96822 USA
推荐引用方式
GB/T 7714
Zheng, Weijun,Kim, Y. Seol,Kaiser, Ralf I.. Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2011,13(35):15749-15754.
APA Zheng, Weijun,Kim, Y. Seol,&Kaiser, Ralf I..(2011).Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,13(35),15749-15754.
MLA Zheng, Weijun,et al."Formation of nitric oxide and nitrous oxide in electron-irradiated (H2O)-O-18/N-2 ice mixtures-evidence for the existence of free oxygen atoms in interstellar and solar system analog ices".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 13.35(2011):15749-15754.

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来源:化学研究所

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