Potential-induced Raman behavior of individual (R)-di-2-naphthylprolinol molecules on a Ag-modified Ag electrode
文献类型：期刊论文
| 作者 | Luo, Zhixun1; Yang, Wensheng2; Luo, Yi3; Peng, Aidong1; Ma, Ying1; Fu, Hongbing1; Yao, Jiannian1; Loo, Boon H.4 |
| 刊名 | JOURNAL OF RAMAN SPECTROSCOPY
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 42期号:5页码:951-957 |
| 关键词 | Potential Raman Sers Ag Electrode (r)-di-2-naphthylprolinol |
| ISSN号 | 0377-0486 |
| DOI | 10.1002/jrs.2819 |
| 英文摘要 | The applicability of surface-enhanced Raman spectroscopy is demonstrated to probe the adsorption behavior of individual molecules on a Ag electrode. High-quality SERS spectra of (R)-di-2-naphthylprolinol (DNP) were obtained from ultradilute solutions (10(-12) M) on the Ag-nanoparticle-modified Ag electrode, which is attributed to the high electromagnetic (EM) effect of the SERS-active system as well as to the strong adsorption and interaction of DNP molecules with Ag. The stable SERS spectra present remarkable potential dependence, which gives evidence for the behavior of individual DNP molecules on the Ag surface. Based on statistical analysis for the probability of DNP molecules located in 'hot spots', we propose an SERS mechanism for individual molecules in the electrode system, in combination with the hot-spot model and orientation of the probemolecules. Copyright (C) 2010 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000291364900011 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71303]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao, Jiannian |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Jilin Univ, Coll Chem, Changchun 130012, Peoples R China 3.Royal Inst Technol, Dept Theoret Chem, S-10691 Stockholm, Sweden 4.Towson Univ, Dept Chem, Towson, MD 21252 USA |
| 推荐引用方式 GB/T 7714 | Luo, Zhixun,Yang, Wensheng,Luo, Yi,et al. Potential-induced Raman behavior of individual (R)-di-2-naphthylprolinol molecules on a Ag-modified Ag electrode[J]. JOURNAL OF RAMAN SPECTROSCOPY,2011,42(5):951-957. |
| APA | Luo, Zhixun.,Yang, Wensheng.,Luo, Yi.,Peng, Aidong.,Ma, Ying.,...&Loo, Boon H..(2011).Potential-induced Raman behavior of individual (R)-di-2-naphthylprolinol molecules on a Ag-modified Ag electrode.JOURNAL OF RAMAN SPECTROSCOPY,42(5),951-957. |
| MLA | Luo, Zhixun,et al."Potential-induced Raman behavior of individual (R)-di-2-naphthylprolinol molecules on a Ag-modified Ag electrode".JOURNAL OF RAMAN SPECTROSCOPY 42.5(2011):951-957. |
入库方式： OAI收割
来源：化学研究所
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