Promoted formation of coordination polyelectrolytes by layer-by-layer assembly
文献类型：期刊论文
| 作者 | Lan, Yuru1; Xu, Limin1; Yan, Yun1,2; Huang, Jianbin1; de Keizer, Arie2; Besseling, Nicolaas A. M.3; Stuart, Martien A. Cohen2 |
| 刊名 | SOFT MATTER
 |
| 出版日期 | 2011 |
| 卷号 | 7期号:7页码:3565-3570 |
| ISSN号 | 1744-683X |
| DOI | 10.1039/c0sm01316a |
| 英文摘要 | Metal mediated coordination polymers offer the opportunity to fabricate devices and materials that are equally important for fundamental research and new technologies. Most coordination polymers were synthesized at the desired stoichiometry. We demonstrate that coordination polyelectrolytes can form in layer-by-layer (LBL) assembled films regardless of the initial metal to bisligand ratio in solution. Upon dipping a substrate alternately into a covalent polylectrolyte solution and then into the mixed solution of Fe(3+) and bisligands, the Fe(3+) to ligand ratio in the LBL film tends to be 1 : 1 and forms polymeric structures even if the ratios in the bulk solution strongly deviate from unity. Our results suggest that layer-by-layer assembly promotes the formation of coordination polyelectrotyes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288677200065 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71357]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Yun |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China 2.Wageningen Univ, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands 3.Delft Univ Technol, Sect Nanostruct Mat, Dept Chem Engn, Delft, Netherlands |
| 推荐引用方式 GB/T 7714 | Lan, Yuru,Xu, Limin,Yan, Yun,et al. Promoted formation of coordination polyelectrolytes by layer-by-layer assembly[J]. SOFT MATTER,2011,7(7):3565-3570. |
| APA | Lan, Yuru.,Xu, Limin.,Yan, Yun.,Huang, Jianbin.,de Keizer, Arie.,...&Stuart, Martien A. Cohen.(2011).Promoted formation of coordination polyelectrolytes by layer-by-layer assembly.SOFT MATTER,7(7),3565-3570. |
| MLA | Lan, Yuru,et al."Promoted formation of coordination polyelectrolytes by layer-by-layer assembly".SOFT MATTER 7.7(2011):3565-3570. |
入库方式： OAI收割
来源：化学研究所
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