Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3
文献类型：期刊论文
| 作者 | Gai, Yanbo1,2; Ge, Maofa1; Wang, Weigang1 |
| 刊名 | ATMOSPHERIC ENVIRONMENT
 |
| 出版日期 | 2011 |
| 卷号 | 45期号:1页码:53-59 |
| 关键词 | Cl Atoms Ozone Rate Coefficient Unsaturated Alcohols |
| ISSN号 | 1352-2310 |
| DOI | 10.1016/j.atmosenv.2010.09.047 |
| 英文摘要 | Reactions of Cl atoms with 3-buten-1-ol, 3-methyl-3-buten-1-ol, 2-methyl-3-buten-1-ol and 4-penten-2-ol were investigated using relative technique with gas chromatograph coupled with flame ionization detection (GC-FID). At 298 +/- 1 K and 1.01 x 10(5) Pa, the rate coefficients measured (in units of 10(-10) cm(3) molecule-(1) s(-1)) were 3.63 +/- 0.49, 4.13 +/- 0.56, 3.51 +/- 0.48, and 3.62 +/- 0.49, respectively. The quoted errors included 2 sigma from the least-squares analysis and also 10% errors caused by the uncertainty of the reference rate coefficients. In addition, rate coefficients for reactions of the unsaturated alcohols with O-3 were determined using absolute method. The values obtained have been presented, compared with those of their alkene structural homologues and discussed. Reactivity trends and atmospheric implications have also been discussed. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000285675600005 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71415]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge, Maofa |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gai, Yanbo,Ge, Maofa,Wang, Weigang. Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3[J]. ATMOSPHERIC ENVIRONMENT,2011,45(1):53-59. |
| APA | Gai, Yanbo,Ge, Maofa,&Wang, Weigang.(2011).Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3.ATMOSPHERIC ENVIRONMENT,45(1),53-59. |
| MLA | Gai, Yanbo,et al."Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O-3".ATMOSPHERIC ENVIRONMENT 45.1(2011):53-59. |
入库方式： OAI收割
来源：化学研究所
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