A Novel Silicon-containing Ethynylarene Resin as Heat-resistant Thermoset
文献类型:期刊论文
作者 | Shi, Song1,2; Yang, Ming3; Luo, Zhenhua3; Han, Weijian3; Hu, Jidong2; Zhao, Tong3; Zhang, Dahai1,2 |
刊名 | POLYMERS & POLYMER COMPOSITES
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出版日期 | 2011 |
卷号 | 19期号:2-3页码:141-147 |
ISSN号 | 0967-3911 |
英文摘要 | A series of novel processable and heat-resistant silicon-containing resins (PSA-E resins) were successfully synthesized by the reaction of 1,3,5-tris-(4-ethynylphenyl)benzene (TEPHB) with silylene-acetylene polymer (PSA resin) with high yields. The molecular structure, thermal curing processes and thermal properties were characterized by FTIR, (HNMR)-H-1, GPC, DSC and TGA. The results indicated that these novel resins could be melted at room temperature and thermally cured at 200-250 degrees C with low exothermal heat. Owing to the complete crosslinking of ethynyl groups, the Td(5) (temperature of 5% weight loss) for all the thermosets are above 500 degrees C, and the overall char yields were above 87% at 900 degrees C under nitrogen. |
语种 | 英语 |
WOS记录号 | WOS:000289542000015 |
出版者 | ISMITHERS |
源URL | [http://ir.iccas.ac.cn/handle/121111/71431] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Shi, Song |
作者单位 | 1.Tianjin Polytech Univ, Tianjin 300160, Peoples R China 2.Aerosp Res Inst Mat & Proc Technol, Natl Key Lab Adv Funct Composite Mat, Beijing 100076, Peoples R China 3.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Shi, Song,Yang, Ming,Luo, Zhenhua,et al. A Novel Silicon-containing Ethynylarene Resin as Heat-resistant Thermoset[J]. POLYMERS & POLYMER COMPOSITES,2011,19(2-3):141-147. |
APA | Shi, Song.,Yang, Ming.,Luo, Zhenhua.,Han, Weijian.,Hu, Jidong.,...&Zhang, Dahai.(2011).A Novel Silicon-containing Ethynylarene Resin as Heat-resistant Thermoset.POLYMERS & POLYMER COMPOSITES,19(2-3),141-147. |
MLA | Shi, Song,et al."A Novel Silicon-containing Ethynylarene Resin as Heat-resistant Thermoset".POLYMERS & POLYMER COMPOSITES 19.2-3(2011):141-147. |
入库方式: OAI收割
来源:化学研究所
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