Synthesis, crystal structure, and different local conformations of pyridine-imide oligomers
文献类型：期刊论文
| 作者 | Zhu, Hengheng1,2; He, Weiwei1,3; Zhan, Chuanlang1; Li, Xiao1; Guan, Zisheng2; Guo, Fengqi3; Yao, Jiannian1 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2011-11-04 |
| 卷号 | 67期号:44页码:8458-8464 |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2011.09.006 |
| 英文摘要 | In this article, we report a new approach toward synthesis of pyridine-imide oligomers (PIOs). Using this approach, both dimer and trimer were one-pot synthesized from acylation of monomeric monoamide with monomeric dichloride. The yield of trimer was dependent on the alkoxyl terminals: it was 30% for methoyl group, whereas it was 95% for 3-chloro-1-propoxyl terminal. Acylation of dimeric monoamide with monomeric dichloride produced trimer, tetramer, and pentamer in a yield of 34%, 33%, and 28%, respectively. The synthesis was proposed to be mediated through an exchange between pyridine-2-carboxamide and pyridine-2-carbonyl chloride, both forming intramolecular or intermolecular hydrogen-bonds between pyridine-nitrogen and pyridine-2-amide hydrogen atoms. Crystal structure from three trimers with different terminal groups was reported. Analysis on the crystal structures revealed that these three trimers had different local conformations. The different local conformations were originated from the structural tunability of the imide unit in either the coplanarity or bond parameters. (C) 2011 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000295957000004 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71459]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Chuanlang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Nanjing Univ Technol, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu Provinc, Peoples R China 3.Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Henan Province, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Hengheng,He, Weiwei,Zhan, Chuanlang,et al. Synthesis, crystal structure, and different local conformations of pyridine-imide oligomers[J]. TETRAHEDRON,2011,67(44):8458-8464. |
| APA | Zhu, Hengheng.,He, Weiwei.,Zhan, Chuanlang.,Li, Xiao.,Guan, Zisheng.,...&Yao, Jiannian.(2011).Synthesis, crystal structure, and different local conformations of pyridine-imide oligomers.TETRAHEDRON,67(44),8458-8464. |
| MLA | Zhu, Hengheng,et al."Synthesis, crystal structure, and different local conformations of pyridine-imide oligomers".TETRAHEDRON 67.44(2011):8458-8464. |
入库方式： OAI收割
来源：化学研究所
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