Syntheses, crystal structures and magnetic properties of two dicopper(II) complexes and a zigzag 1-D Cu(II) complex of a bidentate pyridyl-pyrazole ligand
文献类型：期刊论文
| 作者 | Das, Kinsuk2; Mandal, Tarak Nath3; Roy, Somnath3; Jana, Atanu3; Konar, Saugata3; Liu, Cai-Ming1; Barik, Anil Kumar4; Kar, Susanta Kumar3 |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2011-03-24 |
| 卷号 | 30期号:5页码:715-724 |
| 关键词 | Syntheses Crystal Structures Binuclear Cu(Ii) Complex 1-d Coordination Polymer Magnetic Properties |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2010.12.010 |
| 英文摘要 | Two new dinuclear copper compounds, [Cu-2(pypz)(2)(N-3)(2)(NO3)(2)](1) and [Cu-2(PYPz)(2)(OH)(2)(NO3)(2)](2), and one 1-D polymeric Cu(II) complex, [Cu(pypz)(dca)(3)](n) (3) ['pypz' = (3,5dimethyl-1-(2'-pyridyl)pyrazole) and dca = (dicyanamide)], have been synthesized and characterized crystallographically and spectroscopically. Complex 1 is pseudo-octahedral, adjacent Cu atoms are connected by a pair of mu(1,1) azido groups and the structure is stabilized by pi-pi interactions between two pyridyl moieties from two different neighboring complex molecules. Complexes 2 and 3 are square pyramidal. The hydroxo bridged complex 2 is further stabilized through H-bonding. The 1-D polymeric chain of 3 is bridged by an end-to-end dicyanamide bridge and it propagates along the crystallographic b axis, whilst the polymer chains are stacked one upon another along the crystallographic c axis. Low temperature magnetic measurement shows that complexes 1 and 2 are ferromagnetic (J values are 30.81 and 14.79 cm(-1), respectively), whereas due to larger Cu-Cu distances, complex 3 shows weak ferromagnetism. (C) 2010 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288922700006 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71487]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Cai-Ming |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Haldia Govt Coll, Dept Chem, Debhog 721657, Purba Midnapur, India 3.Univ Calcutta, Univ Coll Sci, Dept Chem, Kolkata 700009, India 4.St Pauls CM Coll, Dept Chem, Kolkata 700009, India |
| 推荐引用方式 GB/T 7714 | Das, Kinsuk,Mandal, Tarak Nath,Roy, Somnath,et al. Syntheses, crystal structures and magnetic properties of two dicopper(II) complexes and a zigzag 1-D Cu(II) complex of a bidentate pyridyl-pyrazole ligand[J]. POLYHEDRON,2011,30(5):715-724. |
| APA | Das, Kinsuk.,Mandal, Tarak Nath.,Roy, Somnath.,Jana, Atanu.,Konar, Saugata.,...&Kar, Susanta Kumar.(2011).Syntheses, crystal structures and magnetic properties of two dicopper(II) complexes and a zigzag 1-D Cu(II) complex of a bidentate pyridyl-pyrazole ligand.POLYHEDRON,30(5),715-724. |
| MLA | Das, Kinsuk,et al."Syntheses, crystal structures and magnetic properties of two dicopper(II) complexes and a zigzag 1-D Cu(II) complex of a bidentate pyridyl-pyrazole ligand".POLYHEDRON 30.5(2011):715-724. |
入库方式： OAI收割
来源：化学研究所
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