Superconcentrated Hydrochloric Acid
文献类型：期刊论文
| 作者 | Huang, Kun2; Zhou, Hui2,3; He, Anqi2; Sun, Yan1,2; Liu, Yufeng2,4; Gao, Xiuxiang2; Zhao, Ying4; Liu, Shaoxuan2; Li, Zhihong5; Hu, Tiandou5 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2011-06-23 |
| 卷号 | 115期号:24页码:7823-7829 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp109551z |
| 英文摘要 | We report the discovery of a potentially useful superconcentrated HCl at ambient temperature and pressure by using a simple surfactant-based reversed micelle system. Surprisingly, the molar ratios of H(+) to H(2)O (denoted as n(H+)/n(H2O)) in superconcentrated HCl can be larger than 5, while the maximum achievable n(H+)/n(H2O) value for conventional saturated HCl aqueous solution (37 wt %) is only about 0.28. Furthermore, both NMR and FT-IR results indicate that a significant amount of HCl remains in the molecular form rather than being ionized into H(+) and Cl(-). The superconcentrated HCl may promote some organic reactions that are not feasible by using conventional 37 wt % HCl solution. For example, addition reaction between C=C and HCl occurs in superconcentrated HCl solution without using catalysts. |
| 语种 | 英语 |
| WOS记录号 | WOS:000291709500013 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71523]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, Yongju |
| 作者单位 | 1.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Soochow Univ, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Dept Polymer Sci & Engn, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 6.Peking Univ, State Key Lab Nucl Phys & Technol, Inst Heavy Ion Phys, Sch Phys, Beijing 100871, Peoples R China 7.Univ Elect Sci & Technol China, Sch Life Sci & Technol, Chengdu 610054, Peoples R China 8.Procter & Gamble Co, W Chester, OH 45069 USA |
| 推荐引用方式 GB/T 7714 | Huang, Kun,Zhou, Hui,He, Anqi,et al. Superconcentrated Hydrochloric Acid[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(24):7823-7829. |
| APA | Huang, Kun.,Zhou, Hui.,He, Anqi.,Sun, Yan.,Liu, Yufeng.,...&Wu, Jinguang.(2011).Superconcentrated Hydrochloric Acid.JOURNAL OF PHYSICAL CHEMISTRY B,115(24),7823-7829. |
| MLA | Huang, Kun,et al."Superconcentrated Hydrochloric Acid".JOURNAL OF PHYSICAL CHEMISTRY B 115.24(2011):7823-7829. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。