Synthesis of vanadium(III) complexes bearing iminopyrrolyl ligands and their role as thermal robust ethylene (co)polymerization catalysts
文献类型：期刊论文
| 作者 | Mu, Jing-Shan1,2; Wang, Yong-Xia1; Li, Bai-Xiang1; Li, Yue-Sheng1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2011 |
| 卷号 | 40期号:14页码:3490-3497 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c0dt01650k |
| 英文摘要 | Bis(imino) pyrrolyl vanadium(III) complexes 2a-e [2,5-C4H2N(CH=NR)(2)]VCl2(THF)(2) [R = C6H5 (2a), 2,6-Me2C6H3 (2b), 2,6-(Pr2C6H3)-Pr-i (2c), 2,4,6-Me3C6H2 (2d), C6F5 (2e)] and bis(iminopyrrolyl) vanadium(III) complex 4f [C4H3N(CH=N-2,6-(PrC6H3)-Pr-i)](2)VCl(THF) have been prepared in good yields from VCl3(THF)(3) by treating with 1.0 and 2.0 equivalent deprotonated ligands in tetrahydrofuran (THF), respectively. These complexes were characterized by FTIR and mass spectra as well as elemental analysis. Structures of 2c and 4f were further confirmed by X-ray crystallographic analysis. DFT calculations indicated the configurations of 2a-e with two nitrogen atoms of the chelating ligand coordinating with vanadium metal centre were more stable in energy. These complexes were employed as catalysts for ethylene polymerization at various reaction conditions. On activation with Et2AlCl, these complexes exhibited high catalytic activities (up to 22.2 kg mmol(-1) (V) h(-1) bar(-1)) even at high temperature, suggesting these catalysts possessed remarkable thermal stability. Moreover, high molecular weight polymer with unimodal molecular weight distributions can be obtained, indicating the polymerization took place in a single-site nature. The copolymerizations of ethylene and 1-hexene with precatalysts 2a-e and 4f were also explored in the presence of Et2AlCl. Catalytic activity, comonomer incorporation, and properties of the resultant polymers can be controlled over a wide range by tuning catalyst structures and reaction parameters. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288677900009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71633]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yue-Sheng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun Branch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mu, Jing-Shan,Wang, Yong-Xia,Li, Bai-Xiang,et al. Synthesis of vanadium(III) complexes bearing iminopyrrolyl ligands and their role as thermal robust ethylene (co)polymerization catalysts[J]. DALTON TRANSACTIONS,2011,40(14):3490-3497. |
| APA | Mu, Jing-Shan,Wang, Yong-Xia,Li, Bai-Xiang,&Li, Yue-Sheng.(2011).Synthesis of vanadium(III) complexes bearing iminopyrrolyl ligands and their role as thermal robust ethylene (co)polymerization catalysts.DALTON TRANSACTIONS,40(14),3490-3497. |
| MLA | Mu, Jing-Shan,et al."Synthesis of vanadium(III) complexes bearing iminopyrrolyl ligands and their role as thermal robust ethylene (co)polymerization catalysts".DALTON TRANSACTIONS 40.14(2011):3490-3497. |
入库方式： OAI收割
来源：化学研究所
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