Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex
文献类型：期刊论文
| 作者 | Ning Zhao-lun1,2; Ding Jin-ying1; Jin Ri-zhe1; Kang Chuan-qing1; Cheng Yan-qin1; Gao Lian-xun1 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2011-01-25 |
| 卷号 | 27期号:1页码:45-48 |
| 关键词 | Asymmetric Catalysis Salen-complex Iodolactonization |
| ISSN号 | 1005-9040 |
| 英文摘要 | A number of salen-metal complexes were prepared and their enantioselective catalytic properties toward the asymmetric iodolactonization of (E)- and (Z)-5-substituted-4-pentenoic acid derivatives were investigated. The catalyst system based on salen-Co(II) complex exhibited moderate to good enantioselectivity with the e.e. value ranging from 53% to 74%, as well as high regioselectivity of delta- vs. gamma-iodolactoncs. The salen-Co(11) complex showed the highest enantioselectivity on the asymmetric iodolactonizations of (Z)-5-substituted-4-pentenoic acid derivatives among these reagent-controlled iodolactonization protocols known so far. |
| 语种 | 英语 |
| WOS记录号 | WOS:000287825400010 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71659]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao Lian-xun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ning Zhao-lun,Ding Jin-ying,Jin Ri-zhe,et al. Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2011,27(1):45-48. |
| APA | Ning Zhao-lun,Ding Jin-ying,Jin Ri-zhe,Kang Chuan-qing,Cheng Yan-qin,&Gao Lian-xun.(2011).Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,27(1),45-48. |
| MLA | Ning Zhao-lun,et al."Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 27.1(2011):45-48. |
入库方式： OAI收割
来源：化学研究所
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