Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation
文献类型：期刊论文
| 作者 | Zhu, Li-Li1; Li, Xiao-Xiao1; Zhou, Wen1; Li, Xin1; Chen, Zili1,2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2011-11-04 |
| 卷号 | 76期号:21页码:8814-8823 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo2015517 |
| 英文摘要 | A new efficient method was developed to transform cyclic alkanols into one-carbon higher homologated ketones using various esters as the leaving groups through gold-catalyzed allylic cation-promoted pinacol-type rearrangement. This reaction, coupled with oxy-Cope rearrangement, provided a new strategy to synthesize five-carbon homologated ring ketones. In addition, using ZnBr2, 2,5-dihydrofuran products were obtained in moderate to good yields via an intramolecular cyclization process. |
| 语种 | 英语 |
| WOS记录号 | WOS:000296206400023 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71781]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Zili |
| 作者单位 | 1.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Li-Li,Li, Xiao-Xiao,Zhou, Wen,et al. Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(21):8814-8823. |
| APA | Zhu, Li-Li,Li, Xiao-Xiao,Zhou, Wen,Li, Xin,&Chen, Zili.(2011).Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation.JOURNAL OF ORGANIC CHEMISTRY,76(21),8814-8823. |
| MLA | Zhu, Li-Li,et al."Divergent Synthetic Routes for Ring Expansion or Cyclization from 1,4-Allylic Diol Derivatives via Gold(I) Catalysis or Zinc(II) Mediation".JOURNAL OF ORGANIC CHEMISTRY 76.21(2011):8814-8823. |
入库方式： OAI收割
来源：化学研究所
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