中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Non-isothermal crystallization of polyamide 6 matrix in all-polyamide composites: crystallization kinetic, melting behavior, and crystal morphology

文献类型:期刊论文

作者Wu, Bozhen1,2; Gong, Ying1,2; Yang, Guisheng1,3
刊名JOURNAL OF MATERIALS SCIENCE
出版日期2011-08-01
卷号46期号:15页码:5184-5191
ISSN号0022-2461
DOI10.1007/s10853-011-5452-5
英文摘要The difference in the melting points of polyamide 66 (PA66) fiber and polyamide 6 (PA6) film permits the preparation of all-polyamide (all-PA) composites by film-packing. Good interface performance and integrated consolidation structure in this all-PA composite are contributed to the similar chemical composition between PA66 fiber and PA6 matrix. In this paper, the non-isothermal crystallization kinetics and melting behaviors of PA6 matrix in all-PA composite are studied by differential scanning calorimetry (DSC), in which the modified Avrami equation, Ozawa model, and Mo equation combining Avrami and Ozawa equation are employed. It is found that the Mo equation exhibits great advantages in treating the non-isothermal crystallization kinetics for both neat PA6 and PA6 matrix in all-PA composite. The crystal morphologies of single PA66 fiber-PA6 composite by polarizing microscope (POM) clearly show a transcrystallinity layer of PA6 around PA66 fiber that proves a remarkable nucleation effect of PA66 fiber surface on the crystallization of PA6 matrix.
语种英语
WOS记录号WOS:000290453900022
出版者SPRINGER
源URL[http://ir.iccas.ac.cn/handle/121111/71843]  
专题中国科学院化学研究所
通讯作者Yang, Guisheng
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Joint Lab Polymer Sci & Technol,Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China
推荐引用方式
GB/T 7714
Wu, Bozhen,Gong, Ying,Yang, Guisheng. Non-isothermal crystallization of polyamide 6 matrix in all-polyamide composites: crystallization kinetic, melting behavior, and crystal morphology[J]. JOURNAL OF MATERIALS SCIENCE,2011,46(15):5184-5191.
APA Wu, Bozhen,Gong, Ying,&Yang, Guisheng.(2011).Non-isothermal crystallization of polyamide 6 matrix in all-polyamide composites: crystallization kinetic, melting behavior, and crystal morphology.JOURNAL OF MATERIALS SCIENCE,46(15),5184-5191.
MLA Wu, Bozhen,et al."Non-isothermal crystallization of polyamide 6 matrix in all-polyamide composites: crystallization kinetic, melting behavior, and crystal morphology".JOURNAL OF MATERIALS SCIENCE 46.15(2011):5184-5191.

入库方式: OAI收割

来源:化学研究所

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