The C-F center dot center dot center dot F-C short contacts in the metal complexes of fluoro-phenyl-acrylic acids
文献类型：期刊论文
| 作者 | Liu, Gui-lei1; Liu, Cai-Ming2; Li, Hui1 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2011-03-01 |
| 卷号 | 184期号:3页码:481-487 |
| 关键词 | Halogen-halogen Interaction Fluoro-cinnamic Acid Supramolecular Chemistry Coordination Polymer Magnetic Exchange Property |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2010.12.022 |
| 英文摘要 | Four new complexes of fluoro-phenyl-acrylic acids (E)-3-(3-fluoro-phenyl)-acrylic acid (L1) [Mn(3)(L1)(6)(L2)(2)]center dot H(2)O center dot CH(3)CN (1), [Zn(2)(L1)(4)(L3)](n) (2), [Mn(L1)(2)(H(2)O)(2)](n). (3) and [Co(L1)(2)(H(2)O)(2)](n) (4) (L2=1,10-phenanthroline, L3=4,4'-bipy) have been synthesized based on the molecular design and research of halogen-halogen interactions (especially fluoro-fluoro contact). The structure analyses reveal that complex 1 is a trinuclear complex, which is blocked by U. Complex 2 is a 1D chain bridged through L3. Complexes 3 and 4 exhibit 2D grid like metal-organic framework structures through carboxylato bridge ligand. Variable-temperature magnetic measurements showed an antiferromagnetic interaction between Mn(11) ions and between Co(II) ions in complexes 3 and 4, respectively. A short C- F center dot center dot center dot F -C contact with a distance of 2.953 angstrom was found between the trinuclear coordination compound 1. (C) 2010 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288587800002 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71919]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Hui |
| 作者单位 | 1.Beijing Inst Technol, Sch Sci, Key Lab Cluster Sci, Minist Educ,Dept Chem, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Gui-lei,Liu, Cai-Ming,Li, Hui. The C-F center dot center dot center dot F-C short contacts in the metal complexes of fluoro-phenyl-acrylic acids[J]. JOURNAL OF SOLID STATE CHEMISTRY,2011,184(3):481-487. |
| APA | Liu, Gui-lei,Liu, Cai-Ming,&Li, Hui.(2011).The C-F center dot center dot center dot F-C short contacts in the metal complexes of fluoro-phenyl-acrylic acids.JOURNAL OF SOLID STATE CHEMISTRY,184(3),481-487. |
| MLA | Liu, Gui-lei,et al."The C-F center dot center dot center dot F-C short contacts in the metal complexes of fluoro-phenyl-acrylic acids".JOURNAL OF SOLID STATE CHEMISTRY 184.3(2011):481-487. |
入库方式： OAI收割
来源：化学研究所
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