A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane
文献类型：期刊论文
| 作者 | Song, Ping; Li, Yaoqi; Li, Wei; He, Bei; Yang, Junzhi; Li, Xingguo |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2011-08-01 |
| 卷号 | 36期号:17页码:10468-10473 |
| 关键词 | Metal-organic Frameworks Heterogeneous Catalyst Ammonia Borane Hydrolysis |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2011.05.120 |
| 英文摘要 | A Co (0) catalyst is synthesized by the reduction of a metal-organic framework (MOF) precursor Co(2)(bdc)(2)(dabco) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2] octane). The amorphous catalyst exhibits highly efficient activity in the hydrolysis of ammonia borane (AB). The dehydrogenation of a 0.32 M aqueous AB solution completes in 1.4 min under room temperature. The porous structure in the MOF is proposed to play a key role. The catalytic effective Co (0) sites are stabilized by the organic molecules, which used to coordinate to Co (II) in the MOP precursor. This work implies that MOFs, with their large surface area and ample pore structures, may serve as ideal precursors for highly efficient heterogeneous catalysts. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000295235200003 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71929]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Xingguo |
| 作者单位 | Peking Univ, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Ping,Li, Yaoqi,Li, Wei,et al. A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2011,36(17):10468-10473. |
| APA | Song, Ping,Li, Yaoqi,Li, Wei,He, Bei,Yang, Junzhi,&Li, Xingguo.(2011).A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,36(17),10468-10473. |
| MLA | Song, Ping,et al."A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 36.17(2011):10468-10473. |
入库方式： OAI收割
来源：化学研究所
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