Well-defined vanadium complexes as the catalysts for olefin polymerization
文献类型:期刊论文
作者 | Wu, Ji-Qian1,2; Li, Yue-Sheng1 |
刊名 | COORDINATION CHEMISTRY REVIEWS
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出版日期 | 2011-10-01 |
卷号 | 255期号:19-20页码:2303-2314 |
关键词 | Vanadium Catalysts Olefin Polymerization Homogeneous Catalysis Polyolefins |
ISSN号 | 0010-8545 |
DOI | 10.1016/j.ccr.2011.01.048 |
英文摘要 | The design and synthesis of well-defined vanadium complexes as efficient catalysts for olefin polymerization remains an attractive project for organometallic and polymeric research. Recently, vanadium complexes with well-defined structures have been explored for olefin (co)polymerization by several groups around the world. This article summarizes our recent progress in well-defined vanadium complexes bearing a variety of chelating beta-enaminoketonato, salicylaldiminato, iminopyrrolide and tetradentate amine trihydroxy ligands, and their applications in ethylene polymerization, ethylene/alpha-olefin copolymerization and ethylene/cycloolefin copolymerization. The application of the optimized catalysts in the copolymerization of ethylene and polar monomer such as 3-huten-1-ol, 5-hexen-1-ol, 10-unclecen-1-ol and 5-norbornene-2-methanol is also discussed. Particular attention has been paid to the relationships between the catalytic behavior and the electronic and geometrical structure of the precatalyst. (C) 2011 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000295250800014 |
出版者 | ELSEVIER SCIENCE SA |
源URL | [http://ir.iccas.ac.cn/handle/121111/71939] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Yue-Sheng |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Changzhou Inst Chem, Changzhou Key Lab Green Chem & Technol, Changzhou 213164, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Ji-Qian,Li, Yue-Sheng. Well-defined vanadium complexes as the catalysts for olefin polymerization[J]. COORDINATION CHEMISTRY REVIEWS,2011,255(19-20):2303-2314. |
APA | Wu, Ji-Qian,&Li, Yue-Sheng.(2011).Well-defined vanadium complexes as the catalysts for olefin polymerization.COORDINATION CHEMISTRY REVIEWS,255(19-20),2303-2314. |
MLA | Wu, Ji-Qian,et al."Well-defined vanadium complexes as the catalysts for olefin polymerization".COORDINATION CHEMISTRY REVIEWS 255.19-20(2011):2303-2314. |
入库方式: OAI收割
来源:化学研究所
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