Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts
文献类型：期刊论文
| 作者 | Fan, Qing-Hua1,2; Ding, Kuiling1,2; Ma, SM |
| 刊名 | ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE
 |
| 出版日期 | 2011 |
| 卷号 | 36页码:207-245 |
| 关键词 | Asymmetric Catalysis Coordination Polymer Dendrimers Immobilization Nanoporous Solids |
| ISSN号 | 1436-6002 |
| DOI | 10.1007/978-3-642-19472-6_7 |
| 英文摘要 | Immobilization of a chiral homogeneous catalyst can in principle facilitate its separation and recycling, and therefore is of considerable interest to both academia and industry. A number of methods have been developed for the immobilization of chiral catalysts, typically including using inert organic or inorganic materials as supports. However, most of the classical immobilized catalysts suffered from inferior catalytic properties to their homogeneous counterparts due to the poor accessibility, random anchoring, or disturbed geometry of the active sites in the solid matrix. In this chapter, we present the progress made in the immobilization of chiral catalysts by focusing on core-functionalized dendrimers in asymmetric catalysis, asymmetric catalysis in nanopores of mesoporous materials, and self-supported chiral catalysts for asymmetric reactions. All the three types of immobilized catalysts possess relatively well-defined structures together with a tunable chiral environment around the catalytically active centers. Representative examples selected from the researches mostly reported by Chinese chemists have demonstrated the high efficiencies and enantioselectivities of these immobilized catalysts. The impacts of supports, such as isolation or confinement effect, on the catalysis will be discussed with emphasis on their application in enantioselective synthesis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000293254500007 |
| 出版者 | SPRINGER-VERLAG BERLIN |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/71963]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ding, Kuiling |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Qing-Hua,Ding, Kuiling,Ma, SM. Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts[J]. ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE,2011,36:207-245. |
| APA | Fan, Qing-Hua,Ding, Kuiling,&Ma, SM.(2011).Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts.ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE,36,207-245. |
| MLA | Fan, Qing-Hua,et al."Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts".ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE 36(2011):207-245. |
入库方式： OAI收割
来源：化学研究所
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