The effects of oxide supports on the low temperature hydrogenation activity of acetone over Pt/Ni bimetallic catalysts on SiO2, gamma-Al2O3 and TiO2
文献类型：期刊论文
| 作者 | Qi, Suitao2; Cheney, Beth A.1; Zheng, Renyang3; Lonergan, William W.1; Yu, Weiting1; Chen, Jingguang G.1 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2011-02-15 |
| 卷号 | 393期号:1-2页码:44-49 |
| 关键词 | Support Effect Pt/ni Bimetallic Catalysts Hydrogenation Acetone Exafs |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2010.11.023 |
| 英文摘要 | Low temperature (308K) hydrogenation of acetone was used as a probe reaction to investigate the support effect on the hydrogenation activity of Pt/Ni bimetallic catalysts supported on TiO2, SiO2 and gamma-Al2O3. The oxide supports significantly affected the catalytic properties of Pt/Ni catalysts, in which Pt/Ni/SiO2 bimetallic catalysts exhibited significantly higher activity than the other two bimetallic catalysts. TEM measurements revealed that the three supported Pt/Ni bimetallic catalysts have similar particle size distribution, while CO chemisorption measurements showed very different chemisorption capacity. Extended X-Ray absorption fine structure (EXAFS) measurements of the Pt L-III-edge indicated that Pt atoms were fully reduced and the Pt-Ni bimetallic bonds were formed on all three catalysts. The extent of Pt-Ni bond formation followed the trend of SiO2 > gamma-Al2O3 > TiO2, which correlated very well with the hydrogenation activity. (c) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000287619400007 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72077]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Jingguang G. |
| 作者单位 | 1.Univ Delaware, Dept Chem Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA 2.Xi An Jiao Tong Univ, Sch Energy & Power Engn, Dept Chem Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Suitao,Cheney, Beth A.,Zheng, Renyang,et al. The effects of oxide supports on the low temperature hydrogenation activity of acetone over Pt/Ni bimetallic catalysts on SiO2, gamma-Al2O3 and TiO2[J]. APPLIED CATALYSIS A-GENERAL,2011,393(1-2):44-49. |
| APA | Qi, Suitao,Cheney, Beth A.,Zheng, Renyang,Lonergan, William W.,Yu, Weiting,&Chen, Jingguang G..(2011).The effects of oxide supports on the low temperature hydrogenation activity of acetone over Pt/Ni bimetallic catalysts on SiO2, gamma-Al2O3 and TiO2.APPLIED CATALYSIS A-GENERAL,393(1-2),44-49. |
| MLA | Qi, Suitao,et al."The effects of oxide supports on the low temperature hydrogenation activity of acetone over Pt/Ni bimetallic catalysts on SiO2, gamma-Al2O3 and TiO2".APPLIED CATALYSIS A-GENERAL 393.1-2(2011):44-49. |
入库方式： OAI收割
来源：化学研究所
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