Synthesis and Physical Properties of beta-Substituted Porphyrin Nickel(II) Derivatives
文献类型：期刊论文
| 作者 | Wan Zhongquan1; Jia Chunyang1; Zhang Jiaqiang1; Li Zi1; Wang Zhihong1; Zhang Guanxin2 |
| 刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2011-03-01 |
| 卷号 | 31期号:3页码:356-361 |
| 关键词 | Porphyrin Cyclic Voltammetry Liquid Crystal Self-assembly Density Functional Theory (Dft) |
| ISSN号 | 0253-2786 |
| 英文摘要 | [5,10,15,20-Tetrakis(4-decaneoxyphenyl)-beta-nitro-porphyrinato]nickel(II) (1) and {5,10,15,20-tetrakis(4-decaneoxyphenyl)-6'-nitroquinoxalino[2,3-b']porphyrinato}nickel(II) (2) are synthesized and confirmed by (1)H NMR, infrared spectroscopy, mass spectrometry (MS), and elemental analysis. The first oxidation potentials of 1 and 2 are positive-shifted and the maximum absorptions of 1 and 2 are red-shifted compared with those of starting compound 3. Differential scanning calorimetry (DSC) results show that only compound 1 possesses liquid crystal property, which behaves the heating monotropic liquid crystal. The self-assembly films of the compounds on Si are studied by atomic force microscopy (AFM), the self-assembly film of 1 is better ordered compared with that of 2. These results indicate that the different physical properties of compounds 1 and 2 are mainly due to their different beta-substituted groups. The observed electronic properties are explained by calculated results based on density functional theory (DFT). |
| 语种 | 英语 |
| WOS记录号 | WOS:000289223000012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72127]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan Zhongquan |
| 作者单位 | 1.Univ Elect Sci & Technol China, Sch Microelect & Solid State Elect, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wan Zhongquan,Jia Chunyang,Zhang Jiaqiang,et al. Synthesis and Physical Properties of beta-Substituted Porphyrin Nickel(II) Derivatives[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2011,31(3):356-361. |
| APA | Wan Zhongquan,Jia Chunyang,Zhang Jiaqiang,Li Zi,Wang Zhihong,&Zhang Guanxin.(2011).Synthesis and Physical Properties of beta-Substituted Porphyrin Nickel(II) Derivatives.CHINESE JOURNAL OF ORGANIC CHEMISTRY,31(3),356-361. |
| MLA | Wan Zhongquan,et al."Synthesis and Physical Properties of beta-Substituted Porphyrin Nickel(II) Derivatives".CHINESE JOURNAL OF ORGANIC CHEMISTRY 31.3(2011):356-361. |
入库方式： OAI收割
来源：化学研究所
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