Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes
文献类型：期刊论文
| 作者 | Cao Yun-Zhu1; Li Zhang-Peng1; Xing Yong-Heng1; Wei Dong-Ming1; Pu Zhi-Feng2; Ge Mao-Fa2; Shi Zhan3 |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2011-05-10 |
| 卷号 | 32期号:5页码:1025-1032 |
| 关键词 | Haloperoxidase Mimic Catalytic Activity Poly(Pyrazolyl) Borate Oxovanadium(Iv) Complex Crystal Structure |
| ISSN号 | 0251-0790 |
| 英文摘要 | In order to mimic the active center of the V-HPOs, we designed and synthesized a series of oxovanadium complexes containing poly (pyrazolyl) borate ligands: VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (HOOC-CH2CH2COO) (1) and VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (C5H4N-COO) (2), which were characterized by X-ray single crystal diffraction. Based on the characteristics that vanadium(V) complexes catalyze phenol red oxidation of bromide into bromophenol blue in a water system under weak-acid condition, the study on catalytic activity about scorpionate oxovanadium(IV) complexes was preformed. The result shows that the scorpionate oxovanadium(IV) complexes exhibit catalytic activity to the extent under the similar conditions. The mechanism of the catalytic reaction was analyzed by molecular orbital theory. |
| 语种 | 英语 |
| WOS记录号 | WOS:000291175800008 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72171]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing Yong-Heng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao Yun-Zhu,Li Zhang-Peng,Xing Yong-Heng,et al. Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(5):1025-1032. |
| APA | Cao Yun-Zhu.,Li Zhang-Peng.,Xing Yong-Heng.,Wei Dong-Ming.,Pu Zhi-Feng.,...&Shi Zhan.(2011).Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(5),1025-1032. |
| MLA | Cao Yun-Zhu,et al."Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.5(2011):1025-1032. |
入库方式： OAI收割
来源：化学研究所
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