Fabrication of Nanofillers into a Granular "Nanosupport'' for Ziegler-Natta Catalysts: Towards Scalable in situ Preparation of Polyolefin Nanocomposites
文献类型：期刊论文
| 作者 | Qin, Yawei1,2; Wang, Ning1,2; Zhou, Yong2; Huang, Yingjuan1; Niu, Hui2; Dong, Jin-Yong2 |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2011-07-15 |
| 卷号 | 32期号:14页码:1052-1059 |
| 关键词 | In Situ Polymerization Morphology Control Nanocomposites Polyolefins Scalable Production |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.201100166 |
| 英文摘要 | This communication reports a strategy for scale-up of an in situ polymerization technique for polyolefin-based nanocomposites preparation, taking layered silicate (clay) and multi-walled carbon nanotubes (MWCNTs) as examples of nanofillers. The strategy is realized by transforming the nanofillers into granular "nanosupports'' for Ziegler-Natta catalysts. With a catalyst to polymer replication effect on particle morphology, the in situ prepared nanocomposites are of controlled granular particle morphology. With the polymer particle morphology controlled, the in situ polymerization technique becomes suitable for industrial olefin polymerization processes for mass production of polyolefin nanocomposites. |
| 语种 | 英语 |
| WOS记录号 | WOS:000292547700003 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72187]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Yingjuan |
| 作者单位 | 1.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Yawei,Wang, Ning,Zhou, Yong,et al. Fabrication of Nanofillers into a Granular "Nanosupport'' for Ziegler-Natta Catalysts: Towards Scalable in situ Preparation of Polyolefin Nanocomposites[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2011,32(14):1052-1059. |
| APA | Qin, Yawei,Wang, Ning,Zhou, Yong,Huang, Yingjuan,Niu, Hui,&Dong, Jin-Yong.(2011).Fabrication of Nanofillers into a Granular "Nanosupport'' for Ziegler-Natta Catalysts: Towards Scalable in situ Preparation of Polyolefin Nanocomposites.MACROMOLECULAR RAPID COMMUNICATIONS,32(14),1052-1059. |
| MLA | Qin, Yawei,et al."Fabrication of Nanofillers into a Granular "Nanosupport'' for Ziegler-Natta Catalysts: Towards Scalable in situ Preparation of Polyolefin Nanocomposites".MACROMOLECULAR RAPID COMMUNICATIONS 32.14(2011):1052-1059. |
入库方式： OAI收割
来源：化学研究所
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