One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)
文献类型：期刊论文
| 作者 | Li, Dongzhen1; Wang, Yang1; Zhang, Wen-Xiong1,2; Zhang, Shaoguang1; Guang, Jie1; Xi, Zhenfeng1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2011-10-10 |
| 卷号 | 30期号:19页码:5278-5283 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om2006613 |
| 英文摘要 | The first synthesis of trisubstituted guanidinium triflates has been achieved by a simple one-step procedure from readily available amines, carbodiimides, and Zn(OTf)(2). X-ray analysis revealed they adopt 1-D chain-like or novel 3-D hydrogen-bonded networks, which have not been reported previously in the solid structure of guanidinium salts. Isolation of a binuclear zinc complex and its subsequent carbodiimide insertion provide the insight into the mechanism for the formation of guanidinium triflates. |
| 语种 | 英语 |
| WOS记录号 | WOS:000295347600025 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72209]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,et al. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)[J]. ORGANOMETALLICS,2011,30(19):5278-5283. |
| APA | Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,Zhang, Shaoguang,Guang, Jie,&Xi, Zhenfeng.(2011).One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2).ORGANOMETALLICS,30(19),5278-5283. |
| MLA | Li, Dongzhen,et al."One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)".ORGANOMETALLICS 30.19(2011):5278-5283. |
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来源：化学研究所
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