Direct conversion of syngas to ethanol over Rh/Mn-supported on modified SBA-15 molecular sieves: Effect of supports
文献类型：期刊论文
| 作者 | Chen, Guochang1,2; Guo, Cun-Yue2; Zhang, Xiaohui1,2; Huang, Zhijun1,2; Yuan, Guoqing1 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2011-03-01 |
| 卷号 | 92期号:3页码:456-461 |
| 关键词 | Rhodium Manganese Co Hydrogenation C-2 Oxygenates Sba-15 Syngas |
| ISSN号 | 0378-3820 |
| DOI | 10.1016/j.fuproc.2010.10.012 |
| 英文摘要 | SBA-15 molecular sieves with a tunable pore size (SBA-15-HCl, SBA-15-HPMo, SBA-15-HPW, and SBA-15-HSiW) were synthesized through adding heteropoly acids to a template and extending crystallization time. Loaded with RhCl3 and Mn(NO3)(2), SBA-15-HPMo catalyzed well the direct conversion of syngas to ethanol. In the first 2 h the CO conversion over the Rh-Mn/SBA-15-HPMo catalyst was up to 100%. Average CO conversion over the SBA-15-HPMo-supported catalyst increased significantly from 42 to 21.9% and selectivity to ethanol from 9.3 to 12.8% compared with the amorphous silica-supported one. The enhanced redox property of the encapsulated Rh and Mn oxides within the mesoporous channels, and multi-dispersed centers formed by confined metal particles contributed to improved catalytic performances. (C) 2010 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000287428900025 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72217]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, Guoqing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, New Mat Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Guochang,Guo, Cun-Yue,Zhang, Xiaohui,et al. Direct conversion of syngas to ethanol over Rh/Mn-supported on modified SBA-15 molecular sieves: Effect of supports[J]. FUEL PROCESSING TECHNOLOGY,2011,92(3):456-461. |
| APA | Chen, Guochang,Guo, Cun-Yue,Zhang, Xiaohui,Huang, Zhijun,&Yuan, Guoqing.(2011).Direct conversion of syngas to ethanol over Rh/Mn-supported on modified SBA-15 molecular sieves: Effect of supports.FUEL PROCESSING TECHNOLOGY,92(3),456-461. |
| MLA | Chen, Guochang,et al."Direct conversion of syngas to ethanol over Rh/Mn-supported on modified SBA-15 molecular sieves: Effect of supports".FUEL PROCESSING TECHNOLOGY 92.3(2011):456-461. |
入库方式： OAI收割
来源：化学研究所
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