New air-stable solution-processed organic n-type semiconductors based on sulfur-rich core-expanded naphthalene diimides
文献类型：期刊论文
| 作者 | Tan, Luxi; Guo, Yunlong; Zhang, Guanxin; Yang, Yang; Zhang, Deqing; Yu, Gui; Xu, Wei; Liu, Yunqi |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 21期号:44页码:18042-18048 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/c1jm13637b |
| 英文摘要 | Among the reported organic n-type semiconductors naphthalene diimide (NDI) derivatives have received more and more attention. In this paper, we report two sulfur-rich expanded NDI derivatives 1 and 2 containing 1,3-dithiole-2-thione-4,5-dithiolate and 1,3-dithiole-2-one-4,5-dithiolate units, respectively. Electrochemical, absorption, spectral and theoretical calculation studies show that LUMO energies of 1 and 2 are lower than that of a typical NDI without functional substitution. OFET devices based on thin-films of 1 and 2 which can be easily solution-processed are fabricated with conventional techniques. The performance of OFET devices of 1 and 2 can be significantly improved by fast annealing (about 30 s) their thin-films in air, with high on/off ratios (10(6)-10(7)) and relatively high electron mobilities of up to 0.05 and 0.04 cm(2) V(-1) s(-1), respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:000296390600071 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72275]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Guanxin |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Labs Organ Solids, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Luxi,Guo, Yunlong,Zhang, Guanxin,et al. New air-stable solution-processed organic n-type semiconductors based on sulfur-rich core-expanded naphthalene diimides[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(44):18042-18048. |
| APA | Tan, Luxi.,Guo, Yunlong.,Zhang, Guanxin.,Yang, Yang.,Zhang, Deqing.,...&Liu, Yunqi.(2011).New air-stable solution-processed organic n-type semiconductors based on sulfur-rich core-expanded naphthalene diimides.JOURNAL OF MATERIALS CHEMISTRY,21(44),18042-18048. |
| MLA | Tan, Luxi,et al."New air-stable solution-processed organic n-type semiconductors based on sulfur-rich core-expanded naphthalene diimides".JOURNAL OF MATERIALS CHEMISTRY 21.44(2011):18042-18048. |
入库方式： OAI收割
来源：化学研究所
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