Multiresponsive Chiroptical Switch of an Azobenzene-Containing Lipid: Solvent, Temperature, and Photoregulated Supramolecular Chirality
文献类型：期刊论文
| 作者 | Duan, Pengfei1; Li, Yuangang2; Li, Liangchun3,4; Deng, Jingen3,4; Liu, Minghua1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2011-04-07 |
| 卷号 | 115期号:13页码:3322-3329 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp110636b |
| 英文摘要 | An azobenzene-containing lipid was designed as a functional organogelator, and its self-assembly as well as the chiroptical properties were investigated. The gelator shows good gelation ability in various organic solvents ranging from polar to nonpolar solvents. Although the molecule did not show a CD signal in the absorption band of azobenzene in solution, supramolecular chirality was observed upon gel formation. Moreover, the supramolecular chirality exhibited a multire-sponse to temperature, photoirradiation, and the solvent polarity. Particularly, positive supramolecular chirality was observed in polar solvents, while it inverted to a negative one in nonpolar solvents. All the responses in relating to the supramolecular chirality were reversible and thus produced a multiresponsive chiroptical switch. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000288885700006 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72305]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Minghua |
| 作者单位 | 1.Chinese Acad Sci, BNLMS, Key Lab Colloid, Inst Chem, Beijing 100190, Peoples R China 2.Xian Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710054, Peoples R China 3.Chinese Acad Sci, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 4.Chinese Acad Sci, Key Lab Asymmetr Synth, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Pengfei,Li, Yuangang,Li, Liangchun,et al. Multiresponsive Chiroptical Switch of an Azobenzene-Containing Lipid: Solvent, Temperature, and Photoregulated Supramolecular Chirality[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(13):3322-3329. |
| APA | Duan, Pengfei,Li, Yuangang,Li, Liangchun,Deng, Jingen,&Liu, Minghua.(2011).Multiresponsive Chiroptical Switch of an Azobenzene-Containing Lipid: Solvent, Temperature, and Photoregulated Supramolecular Chirality.JOURNAL OF PHYSICAL CHEMISTRY B,115(13),3322-3329. |
| MLA | Duan, Pengfei,et al."Multiresponsive Chiroptical Switch of an Azobenzene-Containing Lipid: Solvent, Temperature, and Photoregulated Supramolecular Chirality".JOURNAL OF PHYSICAL CHEMISTRY B 115.13(2011):3322-3329. |
入库方式： OAI收割
来源：化学研究所
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