Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes
文献类型：期刊论文
| 作者 | Feng Tao1; Peng HongMei1; Yao YingMing1; Zhang Yong1; Shen Qi1; Cheng YanXiang2 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 56期号:14页码:1471-1475 |
| 关键词 | Aluminum Beta-ketoiminate Ligand Synthesis Structure Photoluminescence |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-011-4458-3 |
| 英文摘要 | The synthesis, characterization and luminescent properties of aluminum complexes containing a dianionic N-aryloxo functionalized beta-ketoiminate ligand are presented. 4-(2-Hydroxy-5-R-phenyl)imino-2-pentanone (R = Me, (LH2)-H-1; R = tert-butyl, (LH2)-H-2) ligands reacted with AlEt3 in tetrahydrofuran to give the aluminum complexes ((LAlEt)-Al-1)(2) (1) and ((LAlEt)-Al-2)(2) (2) in reasonable isolated yields. X-ray diffraction revealed that complexes 1 and 2 have solvent-free centrosymmetric dimeric structures, and each aluminum center has distorted trigonal bipyramidal geometry. At room temperature, complexes 1 and 2 exhibit blue photoluminescence in acetonitrile with maximum emission wavelengths of 419 and 413 nm, respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:000290274400009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72315]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao YingMing |
| 作者单位 | 1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng Tao,Peng HongMei,Yao YingMing,et al. Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes[J]. CHINESE SCIENCE BULLETIN,2011,56(14):1471-1475. |
| APA | Feng Tao,Peng HongMei,Yao YingMing,Zhang Yong,Shen Qi,&Cheng YanXiang.(2011).Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes.CHINESE SCIENCE BULLETIN,56(14),1471-1475. |
| MLA | Feng Tao,et al."Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes".CHINESE SCIENCE BULLETIN 56.14(2011):1471-1475. |
入库方式： OAI收割
来源：化学研究所
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