Efficient deep-blue emitters comprised of an anthracene core and terminal bifunctional groups for nondoped electroluminescence
文献类型:期刊论文
作者 | Zhu, Minrong2; Wang, Qiang1; Gu, Yu2; Cao, Xiaosong2; Zhong, Cheng2; Ma, Dongge1; Qin, Jingui2; Yang, Chuluo2 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY
![]() |
出版日期 | 2011 |
卷号 | 21期号:17页码:6409-6415 |
ISSN号 | 0959-9428 |
DOI | 10.1039/c1jm10465a |
英文摘要 | Four blue fluorescent host emitters with bifunctional charge transport groups appended to the 9- and 10-positions of the anthracene core have been designed and synthesized. By introducing peripheral bulky aryl-substitution groups to the emissive core, the four compounds show a decreased tendency to crystallise and have high glass transition temperatures ranging from 154 to 226 degrees C. The theoretical calculations reveal that the four self-hosted blue emitters possess noncoplanar structures to suppress intermolecular interaction within the films. The amorphous compounds exhibit strong deep-blue emission both in solution and the solid state. With different end-capping groups, the photophysical and electrochemical properties are tuned to produce efficient deep-blue performance with a simple device architecture. Organic light-emitting diodes (OLEDs) featuring 4 as the emitter achieve a maximum power efficiency of 2.0 lm W(-1) with Commission Internationale de l'Eclairage (CIE) coordinates of (0.16, 0.10) that are very close to the National Television Standards Committee's blue standard. The well-matched energy level between the anode and 4 as well as the intrinsic good charge transport abilities results in a very low driving voltage (2.7 V), making the nondoped deep-blue electroluminescent device power efficient. |
语种 | 英语 |
WOS记录号 | WOS:000289524300044 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.iccas.ac.cn/handle/121111/72393] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ma, Dongge |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Minrong,Wang, Qiang,Gu, Yu,et al. Efficient deep-blue emitters comprised of an anthracene core and terminal bifunctional groups for nondoped electroluminescence[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(17):6409-6415. |
APA | Zhu, Minrong.,Wang, Qiang.,Gu, Yu.,Cao, Xiaosong.,Zhong, Cheng.,...&Yang, Chuluo.(2011).Efficient deep-blue emitters comprised of an anthracene core and terminal bifunctional groups for nondoped electroluminescence.JOURNAL OF MATERIALS CHEMISTRY,21(17),6409-6415. |
MLA | Zhu, Minrong,et al."Efficient deep-blue emitters comprised of an anthracene core and terminal bifunctional groups for nondoped electroluminescence".JOURNAL OF MATERIALS CHEMISTRY 21.17(2011):6409-6415. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。