Ru nanoparticles immobilized on metal-organic framework nanorods by supercritical CO2-methanol solution: highly efficient catalyst
文献类型：期刊论文
| 作者 | Zhao, Yueju; Zhang, Jianling; Song, Jinliang; Li, Jianshen; Liu, Jinli; Wu, Tianbin; Zhang, Peng; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:8页码:2078-2082 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c1gc15340d |
| 英文摘要 | A simple and efficient route for the immobilization of noble metal nanoparticles onto metal-organic framework (MOF) has been designed in this work. The Ru/MOF nanocomposites were prepared using RuCl(3 center dot)3H(2)O as a precursor in supercritical CO2-methanol solution at 200 degrees C. The as-synthesized Ru/MOF composite presented a high catalytic performance for the hydrogenation of cyclohexene and benzene. There was almost no activity loss after the catalyst was reused five times. The intermolecular interactions between the MOF and Ru nanoparticles were investigated by X-ray photoelectron spectra and FT-IR spectra. It was shown that the carboxylate groups of MOF were coordinated to Ru. The formation mechanism of the Ru/MOF nanocomposites in supercritical CO2-methanol solution through an inorganic reaction route was discussed. This method can be easily applied to the synthesis of other MOF-supported metal nanoparticles. |
| 语种 | 英语 |
| WOS记录号 | WOS:000293518300023 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72449]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Yueju |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yueju,Zhang, Jianling,Song, Jinliang,et al. Ru nanoparticles immobilized on metal-organic framework nanorods by supercritical CO2-methanol solution: highly efficient catalyst[J]. GREEN CHEMISTRY,2011,13(8):2078-2082. |
| APA | Zhao, Yueju.,Zhang, Jianling.,Song, Jinliang.,Li, Jianshen.,Liu, Jinli.,...&Han, Buxing.(2011).Ru nanoparticles immobilized on metal-organic framework nanorods by supercritical CO2-methanol solution: highly efficient catalyst.GREEN CHEMISTRY,13(8),2078-2082. |
| MLA | Zhao, Yueju,et al."Ru nanoparticles immobilized on metal-organic framework nanorods by supercritical CO2-methanol solution: highly efficient catalyst".GREEN CHEMISTRY 13.8(2011):2078-2082. |
入库方式： OAI收割
来源：化学研究所
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