Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl
文献类型：期刊论文
| 作者 | Tobon, Yeny A.1; Cozzarin, Melina V.1; Wang, Wei-Gang2; Ge, Mao-Fa2; Della Vedova, Carlos O.1,3; Romano, Rosana M.1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2011-09-15 |
| 卷号 | 115期号:36页码:10203-10210 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp204789h |
| 英文摘要 | ClC(O)SSCl was prepared by an improved method by the reaction of [(CH(3))(2)CHOC(S)](2)S with SO(2)Cl(2) in hexane. The photoelectron spectra in the gas phase present four distinct regions, corresponding to ionizations from electrons formally located at the S, O, and Cl atoms and at the C=O bond. The vibrational IR and Raman spectra of the liquid were interpreted in terms of the most stable syn gauche conformer (the O=C double bond syn with respect to the S-S single bond and the C-S single bond gauche with respect to the S-Cl single bond) in equilibrium with the less stable anti gauche form, both occurring in two enantiomeric forms. The randomization process between the conformers was induced by broad-band UV-visible irradiation in matrix conditions, and several photoproducts were identified by FTIR spectroscopy. The experimental results were complemented by theoretical calculations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000294701300009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72475]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Romano, Rosana M. |
| 作者单位 | 1.Natl Univ La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR,UNLP CONICET,CCT La Plata, RA-1900 La Plata, Argentina 2.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China 3.Univ Nacl Plata, Fac Ciencias Exactas, Dept Quim, LaSeISiC,CIC UNLP CONICET, RA-1897 Gonnet, Argentina |
| 推荐引用方式 GB/T 7714 | Tobon, Yeny A.,Cozzarin, Melina V.,Wang, Wei-Gang,et al. Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(36):10203-10210. |
| APA | Tobon, Yeny A.,Cozzarin, Melina V.,Wang, Wei-Gang,Ge, Mao-Fa,Della Vedova, Carlos O.,&Romano, Rosana M..(2011).Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl.JOURNAL OF PHYSICAL CHEMISTRY A,115(36),10203-10210. |
| MLA | Tobon, Yeny A.,et al."Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl".JOURNAL OF PHYSICAL CHEMISTRY A 115.36(2011):10203-10210. |
入库方式： OAI收割
来源：化学研究所
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