Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids
文献类型：期刊论文
| 作者 | Fan, Xin-Heng1,2; Yang, Lian-Ming1 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2011-03-01 |
| 期号 | 8页码:1467-1471 |
| 关键词 | Cross-coupling Nickel Phosphane Ligands Halides Boron |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201001519 |
| 英文摘要 | Room-temperature Suzuki-Miyaura aryl-aryl cross-coupling reactions have been achieved in high yields by using an easily accessible, air-stable Ni(II)-(sigma-aryl) complex as precatalyst without either the pretreatment of organometallic reagents or the presence of external reductants. The Ni(II) complex, in conjunction with monophosphane ligands such as PCy(3)center dot HBF(4) or PPh(3), allowed the efficient cross-coupling of aryl sulfonates (OTs, OMs) and/or halides (Cl, Br, I) with arylboronic acids at room temperature in toluene/water in the presence of K(2)CO(3) as base. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288129100009 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72477]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Lian-Ming |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, New Mat Lab, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Xin-Heng,Yang, Lian-Ming. Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2011(8):1467-1471. |
| APA | Fan, Xin-Heng,&Yang, Lian-Ming.(2011).Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(8),1467-1471. |
| MLA | Fan, Xin-Heng,et al."Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .8(2011):1467-1471. |
入库方式： OAI收割
来源：化学研究所
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