Bitriazole bridged manganese(II) framework with weak ferromagnet behavior
文献类型:期刊论文
作者 | Jia, Li-Hui1,2; Liu, An-Chang2; Wang, Bing-Wu1; Wang, Zhe-Ming1; Gao, Song1 |
刊名 | POLYHEDRON
![]() |
出版日期 | 2011-11-28 |
卷号 | 30期号:18页码:3112-3115 |
关键词 | Coordination Polymer Manganese Spin Canting Magnetic Properties 3 4 '-bi-1 2 4-triazole |
ISSN号 | 0277-5387 |
DOI | 10.1016/j.poly.2011.02.049 |
英文摘要 | An asymmetric bridging ligand 3,4'-bi-1,2,4-triazole (Hbtr) was used for constructing transition metal coordination polymer, and yielding a manganese(II) compound [Mn(btr)(2)](n) (1) with a unique three-dimensional (3D) framework. Single-crystal X-ray diffraction reveals that 1 crystallizes in the orthorhombic space group Fdd2 and the structure is 3D (3, 6)-connected topological framework constructed from manganese ions and mu(3)-btr ligands. The magnetic investigation for compound 1 shows that it is an anti-ferromagnetically coupled 3D array of high-spin manganese(II) ions with long-range ordering below T = 2.6 K, which is a weak ferromagnetic state due to spin-canting. (C) 2011 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000298522800028 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/72491] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Bing-Wu |
作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Wuhan Inst Chem & Technol, Key Lab Green Chem Proc, Minist Educ, Sch Chem Engn & Pharm, Wuhan 430074, Peoples R China |
推荐引用方式 GB/T 7714 | Jia, Li-Hui,Liu, An-Chang,Wang, Bing-Wu,et al. Bitriazole bridged manganese(II) framework with weak ferromagnet behavior[J]. POLYHEDRON,2011,30(18):3112-3115. |
APA | Jia, Li-Hui,Liu, An-Chang,Wang, Bing-Wu,Wang, Zhe-Ming,&Gao, Song.(2011).Bitriazole bridged manganese(II) framework with weak ferromagnet behavior.POLYHEDRON,30(18),3112-3115. |
MLA | Jia, Li-Hui,et al."Bitriazole bridged manganese(II) framework with weak ferromagnet behavior".POLYHEDRON 30.18(2011):3112-3115. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。