Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
文献类型：期刊论文
| 作者 | Ding, San-Yuan1; Gao, Jia1; Wang, Qiong1,2,3; Zhang, Yuan1; Song, Wei-Guo2,3; Su, Cheng-Yong4; Wang, Wei1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2011-12-14 |
| 卷号 | 133期号:49页码:19816-19822 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja206846p |
| 英文摘要 | Covalent organic frameworks (COFs) are crystalline porous solids with well-defined two- or three-dimensional molecular structures. Although the structural regularity provides this new type of porous material with high potentials in catalysis, no example has been presented so far. Herein, we report the first application of a new COF material, COF-LZU1, for highly efficient catalysis. The easily prepared imine-linked COF-LZU1 possesses a two-dimensional eclipsed layered-sheet structure, making its incorporation with metal ions feasible. Via a simple post-treatment, a Pd(II)-containing COF, Pd/COF-LZU1, was accordingly synthesized, which showed excellent catalytic activity in catalyzing the Suzuki-Miyaura coupling reaction. The superior utility of Pd/COF-LZU1 in catalysis was elucidated by the broad scope of the reactants and the excellent yields (96-98%) of the reaction products, together with the high stability and easy recyclability of the catalyst. We expect that our approach will further boost research on designing and employing functional COF materials for catalysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000298719800048 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72511]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Wei |
| 作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China 4.Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, San-Yuan,Gao, Jia,Wang, Qiong,et al. Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(49):19816-19822. |
| APA | Ding, San-Yuan.,Gao, Jia.,Wang, Qiong.,Zhang, Yuan.,Song, Wei-Guo.,...&Wang, Wei.(2011).Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(49),19816-19822. |
| MLA | Ding, San-Yuan,et al."Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.49(2011):19816-19822. |
入库方式： OAI收割
来源：化学研究所
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