Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D
文献类型：期刊论文
| 作者 | Duan, Zhiming1,2,3; Zhang, Yan4; Zhang, Bin1,2; Zhu, Daoben1,2 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:22页码:6801-6810 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c1ce05668a |
| 英文摘要 | A family of coordination compounds: CoBr2(1,4-dioxane)(2) (1), CoBr2(1,4-dioxane)(2)(H2O)(2) (2), CoBr2(1,4-dioxane)(3)(H2O)(4) (3) and CoBr2(1,4-dioxane)(2)(H2O)(4) (4 (C 2/c) and 5 (I 4(1)/a)) with different dimensions have been crystallized from a solution of CH3OH/1,4-dioxane. The solvent-mediated transformation was observed from the blue kinetically favored 2D compound 1 to the red metastable 1D compound 2, 0D compound 3, and finally to the thermodynamically stable 0D compounds 4 and 5. The hydrogen bonds played a key role in the formation of the different networks of 2-5 with the increasing of the coordinated water molecules. The magnetic measurements showed that 1 was a canted antiferromagnet, and 3-5 acted as antiferromagnets. |
| 语种 | 英语 |
| WOS记录号 | WOS:000296160000033 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72629]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Bin |
| 作者单位 | 1.Chinese Acad Sci, Organ Solid Lab, BNLMS, CMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Peking Univ, Dept Phys, Inst Condensed Matter & Mat Phys, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Zhiming,Zhang, Yan,Zhang, Bin,et al. Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D[J]. CRYSTENGCOMM,2011,13(22):6801-6810. |
| APA | Duan, Zhiming,Zhang, Yan,Zhang, Bin,&Zhu, Daoben.(2011).Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D.CRYSTENGCOMM,13(22),6801-6810. |
| MLA | Duan, Zhiming,et al."Solvent-mediated crystal-to-crystal transformation within the CoBr2 (1,4-dioxane)(m)(H2O)(n) family (m=2, 3; n=0, 2, 4) from 2D to 1D, and 0D".CRYSTENGCOMM 13.22(2011):6801-6810. |
入库方式： OAI收割
来源：化学研究所
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